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  7. Boron tribromide, 1M soln. in dichloromethane

Boron tribromide, 1M soln. in dichloromethane

Catalog No. p-7046544
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AAL14880AC 25 mL
AAL14880AE 100 mL
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Catalog No. AAL14880AC Supplier Thermo Scientific Chemicals Supplier No. L14880AC
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Description

CAS: 10294-33-4 | BBr3 | 250.52 g/mol

Boron tribromide is used as a reactant for luminescent polystyrene derivatives with sterically protected carbazolylborane moieties, high-quality boron-doped graphene via Wurtz-type reductive coupling reaction and micrometer-sized organic molecule-DNA hybrid structures. It is also used in bromination and cyclization reactions to prepare cyclopenta[1,3]cyclopropa[1,2-b]pyrrolizin-8-one. It acts as a liquid boron source used in p-type deposition processes.

This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.

Applications
Boron tribromide is used as a reactant for luminescent polystyrene derivatives with sterically protected carbazolylborane moieties, high-quality boron-doped graphene via Wurtz-type reductive coupling reaction and micrometer-sized organic molecule-DNA hybrid structures. It is also used in bromination and cyclization reactions to prepare cyclopenta[1,3]cyclopropa[1,2-b]pyrrolizin-8-one. It acts as a liquid boron source used in p-type deposition processes.

Solubility
Miscible with ethanol and carbon tetrachloride.

Notes
Moisture sensitive. Reacts violently with water. Incompatible with alcohols, alkali metals, aluminum, sodium oxides and strong bases.

Chemical Identifiers

CAS 10294-33-4
Molecular Formula BBr3
Molecular Weight (g/mol) 250.52
MDL Number MFCD00011312
InChI Key ILAHWRKJUDSMFH-UHFFFAOYSA-N
Synonym boron tribromide, borane, tribromo, boron bromide, tribromoboron, hsdb 327, tribromoboran, boron tribrornide, boron tri bromide, boron tri-bromide
PubChem CID 25134
IUPAC Name tribromoborane
SMILES BrB(Br)Br

Specifications

Quantity 25 mL
UN Number UN3390
Merck Index 14,1347
Solubility Information Miscible with ethanol and carbon tetrachloride.
Formula Weight 250.52
Concentration or Composition (by Analyte or Components) 1M soln. in dichloromethane
Refractive Index 1.434
Sensitivity Moisture sensitive
Density 1.467
Chemical Name or Material Boron tribromide

Safety and Handling

Hazard Category H300+H330-H314-H335-H336-H350-H373
Hazard Statement GHS H Statement
H300-H330-H314-H351
Fatal if swallowed.
Fatal if inhaled.
Causes severe skin burns and eye damage.
Suspected of causing cancer.
Precautionary Statement P201-P202-P260-P264b-P270-P271-P281-P284-P303+P361+P353-P304+P340-P305+P351+P338-P310-P330-P331-P363-P501c
DOTInformation Transport Hazard Class: 6.1; Packing Group: I; Proper Shipping Name: TOXIC BY INHALATION LIQUID, CORROSIVE, N.O.S.
EINECSNumber 233-657-9
TSCA Yes
Recommended Storage Ambient temperatures; Store under Nitrogen

RUO – Research Use Only