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  7. Tetra-n-butylammonium fluoride, 1M soln. in THF

Tetra-n-butylammonium fluoride, 1M soln. in THF

Catalog No. AAA10588AC
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AAA10588AC 25 mL
AAA10588AE 100 mL
AAA10588AP 500 mL
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Catalog No. AAA10588AC Supplier Thermo Scientific Chemicals Supplier No. A10588AC
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Description

CAS: 429-41-4 | C16H36FN | 261.47 g/mol

This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.

Applications
Tetra-n-butylammonium fluoride, 1M soln. in THF is used as a reactant for the preparation of triple monoamine reuptake inhibitors as a new generation of antidepressants, oligoribonucleotides with phosphonate-modified linkages, conjugated dienoic acid esters using Suzuki coupling reactions and polyacetylenic glucosides. It plays an important role in aryl alkyl alcohols through Nozaki-Hiyama allylation catalyzed by chiral bipyridyldiol ligands and chromium trichloride. It is also used as a catalyst for the silylation reactions. In addition, it is used as a source of fluoride ion in organic solvents as well as for the deprotection of silyl ether groups.

Solubility
Miscible with terahydrofuran, acetonitrile, dimethyl sulfoxide and organic solvents.

Notes
Store in a cool place. Hygroscopic. Keep the container tightly closed in a dry and well-ventilated place. Incompatible with oxidizing agents and oxygen.

Chemical Identifiers

CAS 429-41-4
Molecular Formula C16H36FN
Molecular Weight (g/mol) 261.47
MDL Number MFCD00011747
InChI Key FPGGTKZVZWFYPV-UHFFFAOYSA-M
Synonym tetrabutylammonium fluoride, tbaf, tetrabutylazanium fluoride, tetrabutyl ammonium fluoride, tetra-n-butylammonium fluoride, tetrabutylamine, fluoride, n,n,n-tributylbutan-1-aminium fluoride, 1-butanaminium, n,n,n-tributyl-, fluoride, n,n,n-tributyl-1-butanaminium fluoride, 1-butanaminium, n,n,n-tributyl-, fluoride 1:1
PubChem CID 2724141
ChEBI CHEBI:51990
IUPAC Name tetrabutylazanium;fluoride
SMILES [F-].CCCC[N+](CCCC)(CCCC)CCCC

Specifications

Density 0.903
Flash Point −17°C (1°F)
Linear Formula [CH3(CH2)3]4NF
Quantity 25 mL
UN Number UN2924
Beilstein 3570522
Sensitivity Hygroscopic
Solubility Information Miscible with terahydrofuran,acetonitrile,dimethyl sulfoxide and organic solvents.
Formula Weight 261.47
Concentration or Composition (by Analyte or Components) 1M soln. in THF
Chemical Name or Material Tetra-n-butylammonium fluoride
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Safety and Handling

Hazard Category H225-H314-H335-H336-H351-H373
Hazard Statement GHS H Statement
H225-H314-H351-H302-H335
Highly flammable liquid and vapor.
Causes severe skin burns and eye damage.
Suspected of causing cancer.
Harmful if swallowed.
May cause respiratory irritation.
Precautionary Statement P201-P202-P210-P233-P235-P240-P241-P242-P243-P260-P264b-P271-P281-P301+P330+P331-P303+P361+P353-P304+P340-P305+P351+P338-P310-P363-P370+P378q-P501c
DOTInformation Transport Hazard Class: 3; Packing Group: II; Proper Shipping Name: FLAMMABLE LIQUIDS, CORROSIVE, N.O.S.
EINECSNumber 207-057-2
TSCA Yes
Recommended Storage Ambient temperatures

RUO – Research Use Only