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  8. (R)-(+)-2,2'-Bis(diphenylphosphino)-1,1'-binaphthyl, 98%

(R)-(+)-2,2'-Bis(diphenylphosphino)-1,1'-binaphthyl, 98%

Catalog No. AAB23785MD
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250 mg
1 g
5 g
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AAB23785MD 250 mg
AAB2378503 1 g
AAB2378506 5 g
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Catalog No. AAB23785MD Supplier Thermo Scientific Chemicals Supplier No. B23785MD
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Description

CAS: 76189-55-4 | C44H32P2 | 622.69 g/mol

(R)-(+)-2,2'-Bis(diphenylphosphino)-1,1'-binaphthy is used as a chiral ligand for metal mediated asymmetric catalysis.

This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.

Applications
(R)-(+)-2,2′-Bis(diphenylphosphino)-1,1′-binaphthy is used as a chiral ligand for metal mediated asymmetric catalysis.

Solubility
Insoluble in water.

Notes
Air sensitive. Incompatible with oxidizing agents.

Chemical Identifiers

CAS 76189-55-4
Molecular Formula C44H32P2
Molecular Weight (g/mol) 622.69
MDL Number MFCD00010805
InChI Key MUALRAIOVNYAIW-UHFFFAOYSA-N
Synonym binap, r-+-2,2'-bis diphenylphosphino-1,1'-binaphthyl, 2,2'-bis diphenylphosphino-1,1'-binaphthyl, s-binap, s---binap, s---2,2'-bis diphenylphosphino-1,1'-binaphthyl, r-+-binap, r-binap, rac-binap, 2,2'-bis diphenylphosphino-1,1'-binaphthalene
PubChem CID 634876
SMILES C1=CC=C(C=C1)P(C1=CC=CC=C1)C1=CC=C2C=CC=CC2=C1C1=C(C=CC2=CC=CC=C12)P(C1=CC=CC=C1)C1=CC=CC=C1

Specifications

Melting Point 239°C to 241°C
Quantity 250 mg
Beilstein 4914063
Merck Index 14,1223
Optical Rotation +230° (c=0.3 in Toluene)
IUPAC Name [1-(2-diphenylphosphanylnaphthalen-1-yl)naphthalen-2-yl]-diphenylphosphane
Formula Weight 622.69
Percent Purity 98%
Chemical Name or Material (R)-(+)-2,2'-Bis(diphenylphosphino)-1,1'-binaphthyl

Safety and Handling

Hazard Category Warning
Hazard Statement GHS H Statement
H315-H319-H335
Causes skin irritation.
Causes serious eye irritation.
May cause respiratory irritation.
Precautionary Statement GHS P Statement
P261-P280-P305+P351+P338-P304+P340-P405-P501a
Avoid breathing dust/fume/gas/mist/vapors/spray.
Wear protective gloves/protective clothing/eye protection/face protection.
IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing.
Store locked up.
Dispose of contents/container in accordance with local/regional/national/international regulations.

RUO – Research Use Only