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N-Methoxymethyl-N-(trimethylsilylmethyl)benzylamine, 94%
CAS: 93102-05-7 | C13H23NOSi | 237.418 g/mol
$78.92 - $234.78
Chemical Identifiers
| CAS | 93102-05-7 |
|---|---|
| Molecular Formula | C13H23NOSi |
| Molecular Weight (g/mol) | 237.418 |
| MDL Number | MFCD00674005 |
| InChI Key | RPZAAFUKDPKTKP-UHFFFAOYSA-N |
| Synonym | n-methoxymethyl-n-trimethylsilylmethyl benzylamine, n-benzyl-1-methoxy-n-trimethylsilyl methyl methanamine, benzyl methoxymethyl trimethylsilyl methyl amine, benzyl-methoxymethyl-trimethylsilanylmethyl-amine, n-benzyl-n-methoxymethyl-n-trimethylsilylmethylamine, n-benzyl-n-methoxymethyl trimethylsilylmethylamine, n-methoxymethyl phenyl-n-trimethylsilyl methyl methanamine, n-methoxymethyl-n-trimethylsilyl methyl phenyl, n-methoxymethyl-n-trimethylsilylmethyl-benzylamine |
| PubChem CID | 353442 |
| IUPAC Name | N-(methoxymethyl)-1-phenyl-N-(trimethylsilylmethyl)methanamine |
| SMILES | COCN(CC1=CC=CC=C1)C[Si](C)(C)C |
| Catalog Number | Mfr. No. | Quantity | Price | Quantity | |||||
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| Catalog Number | Mfr. No. | Quantity | Price | Quantity | |||||
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AAL1941203
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Thermo Scientific Chemicals
L1941203 |
1 g |
Each for $78.92
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AAL1941206
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Thermo Scientific Chemicals
L1941206 |
5 g |
Each for $234.78
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Description
N-Methoxymethyl-N-(trimethylsilylmethyl)benzylamine forms azomethine ylides which readily undergo [3+2] cycloaddition to α,β-unsaturated esters affording N-benzyl substituted pyrrolidines in good yields. It reacts with asymmetric 1,3-dipolar cycloadditions in the practical, large-scale synthesis of chiral pyrrolidines. It is used in the the synthesis of 3-carboxy-1-azabicyclo[2.2.1]heptane derivatives, an important class of physiologically active compounds.
This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.
ApplicationsN-Methoxymethyl-N-(trimethylsilylmethyl)benzylamine forms azomethine ylides which readily undergo [3+2] cycloaddition to α,Ã-unsaturated esters affording N-benzyl substituted pyrrolidines in good yields. It reacts with asymmetric 1,3-dipolar cycloadditions in the practical, large-scale synthesis of chiral pyrrolidines. It is used in the the synthesis of 3-carboxy-1-azabicyclo[2.2.1]heptane derivatives, an important class of physiologically active compounds.
Solubility
Soluble in chloroform, ethyl acetate.
Notes
Moisture & Light Sensitive. Store away from oxidizing agents.
Chemical Identifiers
| 93102-05-7 | |
| 237.418 | |
| RPZAAFUKDPKTKP-UHFFFAOYSA-N | |
| 353442 | |
| COCN(CC1=CC=CC=C1)C[Si](C)(C)C |
| C13H23NOSi | |
| MFCD00674005 | |
| n-methoxymethyl-n-trimethylsilylmethyl benzylamine, n-benzyl-1-methoxy-n-trimethylsilyl methyl methanamine, benzyl methoxymethyl trimethylsilyl methyl amine, benzyl-methoxymethyl-trimethylsilanylmethyl-amine, n-benzyl-n-methoxymethyl-n-trimethylsilylmethylamine, n-benzyl-n-methoxymethyl trimethylsilylmethylamine, n-methoxymethyl phenyl-n-trimethylsilyl methyl methanamine, n-methoxymethyl-n-trimethylsilyl methyl phenyl, n-methoxymethyl-n-trimethylsilylmethyl-benzylamine | |
| N-(methoxymethyl)-1-phenyl-N-(trimethylsilylmethyl)methanamine |
Specifications
| 93102-05-7 | |
| 76°C (0.3 mmHg) | |
| C13H23NOSi | |
| MFCD00674005 | |
| 4311216 | |
| n-methoxymethyl-n-trimethylsilylmethyl benzylamine, n-benzyl-1-methoxy-n-trimethylsilyl methyl methanamine, benzyl methoxymethyl trimethylsilyl methyl amine, benzyl-methoxymethyl-trimethylsilanylmethyl-amine, n-benzyl-n-methoxymethyl-n-trimethylsilylmethylamine, n-benzyl-n-methoxymethyl trimethylsilylmethylamine, n-methoxymethyl phenyl-n-trimethylsilyl methyl methanamine, n-methoxymethyl-n-trimethylsilyl methyl phenyl, n-methoxymethyl-n-trimethylsilylmethyl-benzylamine | |
| RPZAAFUKDPKTKP-UHFFFAOYSA-N | |
| N-(methoxymethyl)-1-phenyl-N-(trimethylsilylmethyl)methanamine | |
| 353442 | |
| 94% |
| 0.928 | |
| 66°C (150°F) | |
| 1.492 | |
| 1 g | |
| Light and moisture sensitive | |
| Soluble in chloroform,ethyl acetate. | |
| COCN(CC1=CC=CC=C1)C[Si](C)(C)C | |
| 237.418 | |
| 237.42 | |
| N-Methoxymethyl-N-(trimethylsilylmethyl)benzylamine |
Safety and Handling
GHS H Statement
H315-H319-H335-H227
Causes skin irritation.
Causes serious eye irritation.
May cause respiratory irritation.
Combustible liquid.
P210-P235-P261-P264b-P271-P280-P302+P352-P304+P340-P305+P351+P338-P312-P332+P313-P362-P370+P378q-P501c
H227-H315-H319-H335
EINECSNumber : 000-000-0
TSCA : No
Recommended Storage : Keep cold; Store under Nitrogen
RUO – Research Use Only