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  8. Isopropyltriphenylphosphonium iodide, 98+%

Isopropyltriphenylphosphonium iodide, 98+%

Catalog No. p-7020805
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AAA1288109 10 g
AAA1288122 100 g
AAA1288130 250 g
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Catalog No. AAA1288109 Supplier Thermo Scientific Chemicals Supplier No. A1288109
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Description

CAS: 24470-78-8 | C21H22IP | 432.29 g/mol

Useful precursor of isopropylidene unit by Wittig reaction with aldehydes. It is also used in tandem cyclopropanation and Wittig olefination in a synthesis of chrysanthemic acid. Also employed in Wittig and cyclopropanation reactions. It is used as a reactant for total synthesis of heliananes, in the preparation of highly substituted benzene derivatives, synthesis of curcuphenol and elvirol analogs via a retro-aldol reaction as fungicidal agents, 4-substituted methoxylbenzoyl-aryl-thiazoles analogues as potent and orally bioavailable anticancer agents.

This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.

Applications
Useful precursor of isopropylidene unit by Wittig reaction with aldehydes. It is also used in tandem cyclopropanation and Wittig olefination in a synthesis of chrysanthemic acid. Also employed in Wittig and cyclopropanation reactions. It is used as a reactant for total synthesis of heliananes, in the preparation of highly substituted benzene derivatives, synthesis of curcuphenol and elvirol analogs via a retro-aldol reaction as fungicidal agents, 4-substituted methoxylbenzoyl-aryl-thiazoles analogues as potent and orally bioavailable anticancer agents.

Solubility
Solubility in methanol, very faint turbidity.

Notes
Light sensitive and hygroscopic. Store away from oxidizing agents and light. Keep the container tightly closed and place it in a cool, dry and well ventilated condition.

Chemical Identifiers

CAS 24470-78-8
Molecular Formula C21H22IP
Molecular Weight (g/mol) 432.29
MDL Number MFCD00031595
InChI Key HHBXWXJLQYJJBW-UHFFFAOYSA-M
Synonym isopropyltriphenylphosphonium iodide, phosphonium, 1-methylethyl triphenyl-, iodide, isopropyltriphenylphosphanium iodide, isopropyl triphenyl phosphonium iodide, triphenyl propan-2-yl phosphanium iodide, i-propyl triphenylphosphonium iodide, isopropyl triphenylphosphonium iodide, acmc-209gck, ksc493k7j, isopropyltriphenylphosphine iodide
PubChem CID 2723783
IUPAC Name triphenyl(propan-2-yl)phosphanium;iodide
SMILES [I-].CC(C)[P+](C1=CC=CC=C1)(C1=CC=CC=C1)C1=CC=CC=C1

Specifications

Melting Point 195°C to 198°C
Quantity 10 g
Beilstein 3599629
Sensitivity Hygroscopic; Light sensitive
Formula Weight 432.29
Percent Purity ≥98%
Chemical Name or Material Isopropyltriphenylphosphonium iodide

Safety and Handling

Hazard Category H315-H319-H335
Hazard Statement GHS H Statement
H315-H319-H335
Causes skin irritation.
Causes serious eye irritation.
May cause respiratory irritation.
Precautionary Statement P261-P264b-P271-P280-P302+P352-P305+P351+P338-P314-P332+P313-P362-P501c
EINECSNumber 246-281-5
TSCA No
Recommended Storage Ambient temperatures

RUO – Research Use Only