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Diphenyl sulfoxide, 98+%

Numéro de catalogue. AAB2213536
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AAB2213536 500 g
AAB2213514 25 g
AAB2213522 100 g
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Numéro de catalogue. AAB2213536 Fournisseur Thermo Scientific Chemicals Code fournisseur B2213536
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Description

CAS: 945-51-7 | C12H10OS | 202.271 g/mol

Diphenyl sulfoxide is a reagent used as an oxidant and hydroxyl activator in combination with a variety of electrophilic reagents. Efficient glycosidation of a phenyl thiosialoside donor with diphenyl sulfoxide and triflic anhydride in dichloromethane was reported. Direct glycosylations with 1-hydroxy glycosyl donors is made using trifluoromethanesulfonic anhydride and diphenyl sulfoxide. The preparation of triarylsulfonium halides was by the action of aryl Grignard reagents on diphenyl sulfoxide.

This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.

Applications
Diphenyl sulfoxide is a reagent used as an oxidant and hydroxyl activator in combination with a variety of electrophilic reagents. Efficient glycosidation of a phenyl thiosialoside donor with diphenyl sulfoxide and triflic anhydride in dichloromethane was reported. Direct glycosylations with 1-hydroxy glycosyl donors is made using trifluoromethanesulfonic anhydride and diphenyl sulfoxide. The preparation of triarylsulfonium halides was by the action of aryl Grignard reagents on diphenyl sulfoxide.

Solubility
Soluble in water. Soluble in most organic solvents.

Notes
Store in cool place. Keep container tightly closed in a dry and well-ventilated place. Store away from strong oxidizing agents.

Identifiants chimiques

CAS 945-51-7
Molecular Formula C12H10OS
Molecular Weight (g/mol) 202.271
MDL Number MFCD00002085
InChI Key JJHHIJFTHRNPIK-UHFFFAOYSA-N
Synonym diphenyl sulfoxide, phenyl sulfoxide, sulfinyldibenzene, phenylsulfinylbenzene, diphenyl sulphoxide, sulfoxide, diphenyl, diphenylsulfoxide, benzene, 1,1'-sulfinylbis, 1,1'-sulfinyldibenzene, phenylsulfinyl benzene
PubChem CID 13679
IUPAC Name benzenesulfinylbenzene
SMILES C1=CC=C(C=C1)S(=O)C2=CC=CC=C2

Spécifications

Melting Point 69°C to 72°C
Boiling Point 206°C to 208°C (13 mmHg)
Quantity 500 g
Beilstein 1908444
Solubility Information Soluble in water. Soluble in most organic solvents.
Formula Weight 202.28
Percent Purity ≥98%
Chemical Name or Material Diphenyl sulfoxide

Sécurité et manipulation

EINECSNumber 213-415-9
RTECSNumber DA9185000
TSCA Yes
Recommended Storage Ambient temperatures

RUO – Research Use Only