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  8. Dess-Martin periodinane

Dess-Martin periodinane

Catalog No. AAL1577903
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Catalog No. AAL1577903 Supplier Thermo Scientific Chemicals Supplier No. L1577903
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Description

CAS: 87413-09-0 | C13H13IO8 | 424.14 g/mol

Dess Martin periodinane is used to oxidize primary alcohols to aldehydes and secondary alcohols to ketones. It is also used as an oxidant for complexes with multifunctional alcohols. It is actively involved in the oxidation of N-protected-amino alcohols without epimerization and allylic alcohols.

This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.

Applications
Dess Martin periodinane is used to oxidize primary alcohols to aldehydes and secondary alcohols to ketones. It is also used as an oxidant for complexes with multifunctional alcohols. It is actively involved in the oxidation of N-protected-amino alcohols without epimerization and allylic alcohols.

Solubility
Soluble in chloroform, acetone, acetonitrile and methylene chloride. Slightly soluble in ether and hexane.

Notes
Store in cool place. Air and moisture sensitive. Incompatible with strong reducing agents, combustible material and water.

Chemical Identifiers

CAS 87413-09-0
Molecular Formula C13H13IO8
Molecular Weight (g/mol) 424.14
MDL Number MFCD00130127
InChI Key NKLCNNUWBJBICK-UHFFFAOYSA-N
PubChem CID 159087
SMILES CC(=O)O[I]1(OC(C)=O)(OC(C)=O)OC(=O)C2=CC=CC=C12

Specifications

Melting Point 130°C to 132°C (decomposition)
Quantity 1 g
UN Number UN1479
Beilstein 4548207
Sensitivity Air, light, and moisture sensitive
Merck Index 14,2933
Synonym dess-martin periodinane, triacetoxyperiodinane, 1,1,1-triacetoxy-1,1-dihydro-1,2-benziodoxol-3 1h-one, dess-martin reagent, dess-martinperiodinane, dess-martin, dess martin periodinane, dess martin, dess-martin periodane
Solubility Information Soluble in chloroform,acetone,acetonitrile and methylene chloride. Slightly soluble in ether and hexane.
IUPAC Name (1,1-diacetyloxy-3-oxo-1$l^{5},2-benziodoxol-1-yl) acetate
Formula Weight 424.15
Percent Purity ≥95%
Chemical Name or Material Dess-Martin periodinane
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Safety and Handling

Hazard Category H272-H315-H319-H335
Hazard Statement GHS H Statement
H272-H315-H319-H335
May intensify fire; oxidizer.
Causes skin irritation.
Causes serious eye irritation.
May cause respiratory irritation.
Precautionary Statement P210-P220-P221-P261-P264b-P271-P280-P302+P352-P304+P340-P305+P351+P338-P312-P332+P313-P362-P370+P378q-P501c
DOTInformation Transport Hazard Class: 5.1; Packing Group: III; Proper Shipping Name: OXIDIZING SOLID, N.O.S.
TSCA No
Recommended Storage Store at -20°C; Store under Argon

RUO – Research Use Only