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  7. Allyltrimethylsilane, 98+%

Allyltrimethylsilane, 98+%

Numéro de catalogue. AAA1466230
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AAA1466230 250 g
AAA1466209 10 g
AAA1466218 50 g
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Numéro de catalogue. AAA1466230 Fournisseur Thermo Scientific Chemicals Code fournisseur A1466230
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Description

CAS: 762-72-1 | C6H14Si | 114.263 g/mol

Allyltrimethylsilane is involved as a reactant in Hosomi Sakurai reaction for allylation in the presence of Lewis acid. For example, it reacts with cyclohexanone to get 1-allylcyclohexanol. It acts as a nucleophile and is involved in Carbon-Ferrier rearrangement.

This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.

Applications
Allyltrimethylsilane is involved as a reactant in Hosomi Sakurai reaction for allylation in the presence of Lewis acid. For example, it reacts with cyclohexanone to get 1-allylcyclohexanol. It acts as a nucleophile and is involved in Carbon-Ferrier rearrangement.

Solubility
Miscible with organic solvents. Immiscible with water.

Notes
Store in cool place. Incompatible with strong oxidizing agents and acids.

Identifiants chimiques

CAS 762-72-1
Molecular Formula C6H14Si
Molecular Weight (g/mol) 114.263
MDL Number MFCD00008635
InChI Key HYWCXWRMUZYRPH-UHFFFAOYSA-N
Synonym allyltrimethylsilane, silane, trimethyl-2-propenyl, trimethylallylsilane, silane, allyltrimethyl, allyl trimethylsilane, unii-8b84c337vf, ccris 2649, allyl trimethyl silane, 3-trimethylsilyl propene, allytrimethylsilane
PubChem CID 69808
IUPAC Name trimethyl(prop-2-enyl)silane
SMILES C[Si](C)(C)CC=C

Spécifications

Boiling Point 85°C to 86°C
Quantity 250 g
UN Number UN1993
Beilstein 906755
Flash Point −10°C (14°F)
Solubility Information Miscible with organic solvents. Immiscible with water.
Formula Weight 114.27
Percent Purity ≥98%
Refractive Index 1.408
Density 0.717
Chemical Name or Material Allyltrimethylsilane
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Sécurité et manipulation

Hazard Category H225-H315-H319-H335
Hazard Statement GHS H Statement
H225-H315-H319-H335
Highly flammable liquid and vapour.
Causes skin irritation.
Causes serious eye irritation.
May cause respiratory irritation.
Precautionary Statement P210-P233-P235-P240-P241-P242-P243-P261-P264b-P271-P280-P303+P361+P353-P304+P340-P305+P351+P338-P312-P332+P313-P363-P370+P378q-P501c
DOTInformation Transport Hazard Class: 3; Packing Group: II; Proper Shipping Name: FLAMMABLE LIQUIDS, N.O.S.
EINECSNumber 212-104-5
TSCA Yes
Recommended Storage Ambient temperatures

RUO – Research Use Only