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Allylpalladium(II) chloride dimer, Pd 56.0% min, Thermo Scientific Chemicals

Supplier:  Thermo Scientific Chemicals 01000501

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Catalog No. AA1000501


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Description

Description

Allylpalladium(II) chloride dimer is used as an important catalyst in Heck reaction. It reacts with cyclopentadienyl anion to give cyclopentadienyl allyl palladium. It acts as a precatalyst for asymmetric and cross-coupling catalysis. Further, it is used in the preparation of 1,4-diallyl-1,2-dihydroisoquinolines. It is also employed as a catalyst for greener Buchwald-Hartwig coupling reaction and involved in the synthesis of cationic palladium catalysts. In addition, it takes part in preparation of -heterocyclic carbene-palladium-eta3-allyl chloride complex, which is an efficient catalyst for the Suzuki-Miyaura cross-coupling reactions in synthetic chemistry.

This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.

Specifications

Specifications

Allylpalladium(II) chloride dimer
120°C (decomposition)
C6H10Cl2Pd2
0.25 g
Air and moisture sensitive
Very soluble in dichloromethane and dichloroethane; Slightly soluble in toluene,insoluble in waterSoluble in chloroform,benzene,acetone and dichloromethane,dichloroethane and methanol; Slightly soluble in toluene; Insoluble in water.
Cl[Pd].Cl[Pd].c:c:c.c:c:c
365.89
365.85
Powder
12012-95-2
Yellow
MFCD00044874
4124623
allylpalladium chloride dimer, bis allyl dichlorodipalladium, diallyldipalladium dichloride, palladium allyl chloride dimer, diallydichlorodipalladium, pi-allyl palladium chloride, allylpalladium ii chloride, bis chloro-pi-allylpalladium, allyl palladium chloride dimer, bis pi-allyl chloropalladium
PENAXHPKEVTBLF-UHFFFAOYSA-L
chloropalladium(1+);prop-1-ene
61538
Pd 56.0% min.

Chemical Identifiers

12012-95-2
365.89
PENAXHPKEVTBLF-UHFFFAOYSA-L
61538
Cl[Pd].Cl[Pd].c:c:c.c:c:c
C6H10Cl2Pd2
MFCD00044874
allylpalladium chloride dimer, bis allyl dichlorodipalladium, diallyldipalladium dichloride, palladium allyl chloride dimer, diallydichlorodipalladium, pi-allyl palladium chloride, allylpalladium ii chloride, bis chloro-pi-allylpalladium, allyl palladium chloride dimer, bis pi-allyl chloropalladium
chloropalladium(1+);prop-1-ene
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Safety and Handling

Safety and Handling

GHS H Statement
H315-H319-H335
Causes skin irritation.
Causes serious eye irritation.
May cause respiratory irritation.

P264b-P280-P302+P352-P305+P351+P338-P332+P313-P362

H315-H319

EINECSNumber : 234-579-8

RTECSNumber : RT3510000

TSCA : No

storageNote1 : 2°C to 8°C

Recommended Storage : Keep cold; Store under Nitrogen

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