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2-(Ethoxycarbonyl)ethylzinc bromide, 0.5M in THF

Catalog No. AAH26739AD
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AAH26739AD 50 mL
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Catalog No. AAH26739AD Supplier Thermo Scientific Chemicals Supplier No. H26739AD
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CAS: 193065-68-8 | C5H10BrO2Zn- | 247.417 g/mol

This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.

Applications
In many of the reactions, organozinc compounds appear as intermediates. Some of the synthetic uses of organozinc compounds are: for the stereo selective alkylation reaction of cyclic ketones, conjugate addition reaction to alpha, be

Chemical Identifiers

CAS 193065-68-8
Molecular Formula C5H10BrO2Zn-
Molecular Weight (g/mol) 247.417
MDL Number MFCD00671976
InChI Key APUPJTIEDQLKSC-UHFFFAOYSA-M
Synonym 2-ethoxycarbonyl ethylzinc bromide, 0.5m in thf
PubChem CID 131668631
IUPAC Name ethyl propanoate;zinc;bromide
SMILES CCC(=O)OCC.[Zn].[Br-]

Specifications

Density 0.972
Flash Point −17°C (1°F)
Quantity 50 mL
UN Number UN3399
Sensitivity Air and moisture sensitive; May form a precipitate
Solubility Information Reacts with water.
Formula Weight 246.42
Chemical Name or Material 2-(Ethoxycarbonyl)ethylzinc bromide
Hazard Category H225-H260-H302-H314-H335-H336-H351
Hazard Statement GHS H Statement
H225-H261-H314-H351-H335
Highly flammable liquid and vapor.
In contact with water releases flammable gas.
Causes severe skin burns and eye damage.
Suspected of causing cancer.
May cause respiratory irritation.
Precautionary Statement P201-P202-P210-P223-P231+P232-P233-P235-P240-P241-P242-P243-P260-P264b-P270-P271-P281-P303+P361+P353-P304+P340-P305+P351+P338-P310-P330-P331-P335+P334-P363-P370+P378q-P501c
DOTInformation Transport Hazard Class: 4.3; Packing Group: II; Proper Shipping Name: ORGANOMETALLIC SUBSTANCE, LIQUID, WATER-REACTIVE, FLAMMABLE
TSCA No
Recommended Storage Keep cold; Store under Argon

RUO – Research Use Only