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1-(Triisopropylsilyl)pyrrole, 95%
CAS: 87630-35-1 | C13H25NSi | 223.44 g/mol
$175.29 - $582.55
Chemical Identifiers
| CAS | 87630-35-1 |
|---|---|
| Molecular Formula | C13H25NSi |
| Molecular Weight (g/mol) | 223.44 |
| MDL Number | MFCD00054932 |
| InChI Key | FBQURXLBJJNDBX-UHFFFAOYSA-N |
| Synonym | 1-triisopropylsilyl pyrrole, 1-triisopropylsilyl-1h-pyrrole, n-triisopropylsilylpyrrole, 1h-pyrrole, 1-tris 1-methylethyl silyl, tri propan-2-yl-pyrrol-1-ylsilane, 1-tris propan-2-yl silyl-1h-pyrrole, pubchem9194, 1-triisopropylsilylpyrrole, 1-triisoproylsilyl-pyrrole, acmc-1bkd7 |
| PubChem CID | 145136 |
| IUPAC Name | tri(propan-2-yl)-pyrrol-1-ylsilane |
| SMILES | CC(C)[Si](C(C)C)(C(C)C)N1C=CC=C1 |
| Catalog Number | Mfr. No. | Quantity | Price | Quantity | |||||
|---|---|---|---|---|---|---|---|---|---|
| Catalog Number | Mfr. No. | Quantity | Price | Quantity | |||||
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AAL1315206
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Thermo Scientific Chemicals
L1315206 |
5 g |
Each for $175.29
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AAL1315214
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Thermo Scientific Chemicals
L1315214 |
25 g |
Each for $582.55
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Description
1-(Triisopropylsilyl)pyrrole may be employed as reagent in perfluoroalkylation and Vilsmeier formylation reactions. It may be used in the preparation of ethyl 2-(2,4-dinitrophenylhydrazono]-3-[ 1-(triisopropylsily1)-pyrrol-2-yflpropanoate; heterocyclic base, 3-nitropyrrole and 3-nitropyrrole, required for the synthesis of 1 -(2?-deoxy-β-D-ribofuranosyl)-3-nitropyrrole. It participates in various electrophilic substitution reactions specifically at β-position, via reaction with various electrophilic reagents (Br+, I+,NO2+,etc).
This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.
Applications1-(Triisopropylsilyl)pyrrole may be employed as reagent in perfluoroalkylation and Vilsmeier formylation reactions. It may be used in the preparation of ethyl 2-(2,4-dinitrophenylhydrazono]-3-[ 1-(triisopropylsily1)-pyrrol-2-yflpropanoate; heterocyclic base, 3-nitropyrrole and 3-nitropyrrole, required for the synthesis of 1 -(2′-deoxy-β-D-ribofuranosyl)-3-nitropyrrole. It participates in various electrophilic substitution reactions specifically at β-position, via reaction with various electrophilic reagents (Br+, I+,NO2+,etc).
Solubility
Not miscible in water.
Notes
Moisture sensitive. Incompatible with oxidizing agents.
Chemical Identifiers
| 87630-35-1 | |
| 223.44 | |
| FBQURXLBJJNDBX-UHFFFAOYSA-N | |
| 145136 | |
| CC(C)[Si](C(C)C)(C(C)C)N1C=CC=C1 |
| C13H25NSi | |
| MFCD00054932 | |
| 1-triisopropylsilyl pyrrole, 1-triisopropylsilyl-1h-pyrrole, n-triisopropylsilylpyrrole, 1h-pyrrole, 1-tris 1-methylethyl silyl, tri propan-2-yl-pyrrol-1-ylsilane, 1-tris propan-2-yl silyl-1h-pyrrole, pubchem9194, 1-triisopropylsilylpyrrole, 1-triisoproylsilyl-pyrrole, acmc-1bkd7 | |
| tri(propan-2-yl)-pyrrol-1-ylsilane |
Specifications
| 87630-35-1 | |
| 78°C (0.4 mmHg) | |
| C13H25NSi | |
| MFCD00054932 | |
| 3540663 | |
| 1-triisopropylsilyl pyrrole, 1-triisopropylsilyl-1h-pyrrole, n-triisopropylsilylpyrrole, 1h-pyrrole, 1-tris 1-methylethyl silyl, tri propan-2-yl-pyrrol-1-ylsilane, 1-tris propan-2-yl silyl-1h-pyrrole, pubchem9194, 1-triisopropylsilylpyrrole, 1-triisoproylsilyl-pyrrole, acmc-1bkd7 | |
| FBQURXLBJJNDBX-UHFFFAOYSA-N | |
| tri(propan-2-yl)-pyrrol-1-ylsilane | |
| 145136 | |
| 95% |
| 0.904 | |
| 106°C (222°F) | |
| 1.492 | |
| 5 g | |
| Moisture sensitive | |
| Not miscible in water. | |
| CC(C)[Si](C(C)C)(C(C)C)N1C=CC=C1 | |
| 223.44 | |
| 223.44 | |
| 1-(Triisopropylsilyl)pyrrole |
Safety and Handling
GHS H Statement
H302
Harmful if swallowed.
P261-P264b-P270-P271-P280i-P301+P312-P304+P340-P305+P351+P338-P312-P330-P501c
H302+H332-H319
TSCA : No
Recommended Storage : Ambient temperatures
RUO – Research Use Only