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  8. m-Anisidine, 98%

m-Anisidine, 98%

Catalog No. p-7081025
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Catalog No. Quantity
AAA1081518 50 g
AAA1081530 250 g
AAA108150B 1000 g
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Catalog No. AAA1081518 Supplier Thermo Scientific Chemicals Supplier No. A1081518
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Description

CAS: 536-90-3 | C7H9NO | 123.155 g/mol

The unusually large amount of dibromo product produced upon bromination of m-anisidine may be attributed to the two doubly activeated positions. The best enantioselectivity of 97 % ee was observed for the reaction of m-anisidine in organocatalytic asymmetric three-component cyclization of cinnamaldehydes and primary amines with 1, 3-Dicarbonyl Compounds. Evidence for the control of 2nd-harmonic generation activities from the x-ray crystal-structures of the complexes of l-tartaric acid with m-anisidine and p-toluidine was determined.

This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.

Applications
The unusually large amount of dibromo product produced upon bromination of m-anisidine may be attributed to the two doubly activeated positions. The best enantioselectivity of 97 % ee was observed for the reaction of m-anisidine in organocatalytic asymmetric three-component cyclization of cinnamaldehydes and primary amines with 1, 3-Dicarbonyl Compounds. Evidence for the control of 2nd-harmonic generation activities from the x-ray crystal-structures of the complexes of l-tartaric acid with m-anisidine and p-toluidine was determined.

Solubility
Soluble in water(18g/L).

Notes
Light Sensitive. Store in cool place. Keep container tightly closed in a dry and well-ventilated place. Store away from strong oxidizing agents.

Chemical Identifiers

CAS 536-90-3
Molecular Formula C7H9NO
Molecular Weight (g/mol) 123.155
MDL Number MFCD00007783
InChI Key NCBZRJODKRCREW-UHFFFAOYSA-N
Synonym m-anisidine, 3-aminoanisole, m-methoxyaniline, 3-methoxybenzenamine, 3-anisidine, m-aminoanisole, benzenamine, 3-methoxy, m-anisylamine, 1-amino-3-methoxybenzene, unii-jxa144kx2i
PubChem CID 10824
IUPAC Name 3-methoxyaniline
SMILES COC1=CC=CC(=C1)N

Specifications

Melting Point -1°C
Density 1.101
Boiling Point 250°C to 251°C
Flash Point 126°C (258°F)
Odor Characteristic
Refractive Index 1.581
Quantity 50 g
UN Number UN2431
Beilstein 386119
Sensitivity Light sensitive
Merck Index 14,667
Solubility Information Soluble in water(18g/L).
Formula Weight 123.16
Percent Purity 98%
Chemical Name or Material m-Anisidine
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Safety and Handling

Hazard Category H302+H332-H311-H373
Hazard Statement GHS H Statement
H311-H373-H302-H332
Toxic in contact with skin.
May cause damage to organs through prolonged or repeated exposure.
Harmful if swallowed.
Harmful if inhaled.
Precautionary Statement P260-P264b-P270-P271-P280-P301+P312-P302+P352-P304+P340-P312-P314-P330-P361-P363-P501c
DOTInformation Transport Hazard Class: 6.1; Packing Group: III; Proper Shipping Name: ANISIDINES
EINECSNumber 208-651-4
RTECSNumber BZ5408000
TSCA Yes
Recommended Storage Ambient temperatures

RUO – Research Use Only