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Dodecacarbonyltriruthenium, 99%
Carbonylation | CAS: 15243-33-1 | C12O12Ru3 | 639.33 g/mol
Supplier: Thermo Scientific Chemicals 01050703
Description
A H-transfer catalyst. It is used in carbonylation catalysis of the allylic amination of unactivated olefins by nitroarenes, reductive carbonylation of mononitro aromatic compounds to carbamates, and as a catalyst for cycloaddition reactions. It is employed as a precursor for the synthesis of Ru nanoparticles. Catalyst used in the intermolecular [3+2+1] cycloaddition of alpha,beta-unsaturated ketones with silylacetylenes and carbon monoxide, to produce alpha-pyrones. Catalyzes the coupling of silanes with thiols, alcohols and amines with high turnover number (TON) and high turnover frequency (TOF).
This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.
Specifications
| Dodecacarbonyltriruthenium | |
| ∼150°C (decomposition) | |
| C12O12Ru3 | |
| MFCD00011209 | |
| UN3466 | |
| Sparingly soluble in hydrocarbons (e;g; hexane,cyclohexane,benzene) and acetone. | |
| [C-]#[O+].[C-]#[O+].[C-]#[O+].[C-]#[O+].[C-]#[O+].[C-]#[O+].[C-]#[O+].[C-]#[O+].[C-]#[O+].[C-]#[O+].[C-]#[O+].[C-]#[O+].[Ru]1[Ru][Ru]1 | |
| 639.33 | |
| 99% |
| 15243-33-1 | |
| Orange | |
| Ru3(CO)12 | |
| 1 g | |
| Ruthenium carbonyl; Triruthenium dodecacarbonyl | |
| NQZFAUXPNWSLBI-UHFFFAOYSA-N | |
| cyclotriruthenium; dodecakis(methanidylidyneoxidanium) | |
| 639.33 | |
| Crystalline |
Chemical Identifiers
| 15243-33-1 | |
| 639.33 | |
| NQZFAUXPNWSLBI-UHFFFAOYSA-N | |
| cyclotriruthenium; dodecakis(methanidylidyneoxidanium) |
| C12O12Ru3 | |
| MFCD00011209 | |
| Ruthenium carbonyl; Triruthenium dodecacarbonyl | |
| [C-]#[O+].[C-]#[O+].[C-]#[O+].[C-]#[O+].[C-]#[O+].[C-]#[O+].[C-]#[O+].[C-]#[O+].[C-]#[O+].[C-]#[O+].[C-]#[O+].[C-]#[O+].[Ru]1[Ru][Ru]1 |
Safety and Handling
GHS H Statement
H331
Toxic if inhaled.
GHS P Statement
P261-P304+P340-P311-P405-P403+P233-P501a
Avoid breathing dust/fume/gas/mist/vapors/spray.
IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing.
Call a POISON CENTER or doctor/physician.
Store locked up.
Store in a well-ventilated place.
Keep container tightly closed.
Dispose of contents/container in accordance with local/regional/national/international regulations.
Danger
DOTInformation : Transport Hazard Class: 6.1; Packing Group: III; Proper Shipping Name: METAL CARBONYLS, SOLID, N.O.S.
EINECSNumber : 239-287-4
TSCA : Yes
Recommended Storage : Ambient temperatures
RUO – Research Use Only