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  8. Diphenyliodonium hexafluorophosphate, 98%

Diphenyliodonium hexafluorophosphate, 98%

Catalog No. aaa1793430
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Quantity:
10 g
250 g
50 g
Catalog No. Quantity
AAA1793430 250 g
AAA1793409 10 g
AAA1793418 50 g
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Catalog No. AAA1793430

Supplier: Thermo Scientific Chemicals A1793430

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Description

CAS: 58109-40-3 | C12H10I | 281.12 g/mol

Diphenyliodonium hexafluorophosphate is used as cationic photoinitiator and photoacid generator. It acts as a catalyst for the photochemical polymerization of various monomers. Further, it used as arylating reagent as well as an oxidant in organic synthesis.

This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.

Applications
Diphenyliodonium hexafluorophosphate is used as cationic photoinitiator and photoacid generator. It acts as a catalyst for the photochemical polymerization of various monomers. Further, it used as arylating reagent as well as an oxidant in organic synthesis.

Solubility
Soluble in tetrahydrofuran, ethyl acetate, methanol, acetonitrile, dimethylformamide, dimethyl carbonate. Sparingly soluble in chloroform and dichloromethane. Insoluble in pentanes, hexanes, toluene and diethyl ether.

Notes
Light sensitive and hygroscopic. Incompatible with strong acids.

Chemical Identifiers

CAS 58109-40-3
Molecular Formula C12H10I
Molecular Weight (g/mol) 281.12
MDL Number MFCD00061398
InChI Key OZLBDYMWFAHSOQ-UHFFFAOYSA-N
Synonym diphenyliodonium hexafluorophosphate, diphenyliodanium hexafluorophosphate, diphenyliodonium hexafluorophosphate v, iodonium, diphenyl-, hexafluorophosphate 1-, iodonium, diphenyl-, hexafluorophosphate 1-1:1, diphenyliodonium pf6, dpihfp, acmc-209m2o, phi + pf6-, diphenyliodanium; hexafluoro-$l^ 5-phosphanuide
PubChem CID 2737136
IUPAC Name diphenyliodanium
SMILES [I+](C1=CC=CC=C1)C1=CC=CC=C1

Specifications

Melting Point 139°C to 144°C
Quantity 250 g
UN Number UN2811
Sensitivity Light sensitive
Solubility Information Soluble in tetrahydrofuran,ethyl acetate,methanol,acetonitrile,dimethylformamide,dimethyl carbonate. Sparingly soluble in chloroform and dichloromethane. Insoluble in pentanes,hexanes,toluene and diethyl ether.
Formula Weight 426.08
Percent Purity 98%
Chemical Name or Material Diphenyliodonium hexafluorophosphate

Safety and Handling

Hazard Category H314-H335
Hazard Statement GHS H Statement
H331-H302-H312-H315-H319-H335
Toxic if inhaled.
Harmful if swallowed.
Harmful in contact with skin.
Causes skin irritation.
Causes serious eye irritation.
May cause respiratory irritation.
Precautionary Statement P260-P264b-P271-P280-P301+P330+P331-P303+P361+P353-P304+P340-P305+P351+P338-P310-P363-P501c
DOTInformation Hazard Class: 8; Packaging Group: II
EINECSNumber 261-134-5
TSCA Yes
Recommended Storage Ambient temperatures

RUO – Research Use Only