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Allylpalladium(II) chloride dimer, Pd 56.0% min
CAS: 12012-95-2 | C6H10Cl2Pd2 | 365.89 g/mol
Supplier: Thermo Scientific Chemicals 01000501
Description
Allylpalladium(II) chloride dimer is used as an important catalyst in Heck reaction. It reacts with cyclopentadienyl anion to give cyclopentadienyl allyl palladium. It acts as a precatalyst for asymmetric and cross-coupling catalysis. Further, it is used in the preparation of 1,4-diallyl-1,2-dihydroisoquinolines. It is also employed as a catalyst for greener Buchwald-Hartwig coupling reaction and involved in the synthesis of cationic palladium catalysts. In addition, it takes part in preparation of -heterocyclic carbene-palladium-eta3-allyl chloride complex, which is an efficient catalyst for the Suzuki-Miyaura cross-coupling reactions in synthetic chemistry.
This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.
Specifications
| Allylpalladium(II) chloride dimer | |
| 120°C (decomposition) | |
| C6H10Cl2Pd2 | |
| 0.25 g | |
| Air and moisture sensitive | |
| Very soluble in dichloromethane and dichloroethane; Slightly soluble in toluene,insoluble in waterSoluble in chloroform,benzene,acetone and dichloromethane,dichloroethane and methanol; Slightly soluble in toluene; Insoluble in water. | |
| Cl[Pd].Cl[Pd].c:c:c.c:c:c | |
| 365.89 | |
| 365.85 | |
| Powder |
| 12012-95-2 | |
| Yellow | |
| MFCD00044874 | |
| 4124623 | |
| allylpalladium chloride dimer, bis allyl dichlorodipalladium, diallyldipalladium dichloride, palladium allyl chloride dimer, diallydichlorodipalladium, pi-allyl palladium chloride, allylpalladium ii chloride, bis chloro-pi-allylpalladium, allyl palladium chloride dimer, bis pi-allyl chloropalladium | |
| PENAXHPKEVTBLF-UHFFFAOYSA-L | |
| chloropalladium(1+);prop-1-ene | |
| 61538 | |
| Pd 56.0% min. |
Chemical Identifiers
| 12012-95-2 | |
| 365.89 | |
| PENAXHPKEVTBLF-UHFFFAOYSA-L | |
| 61538 | |
| Cl[Pd].Cl[Pd].c:c:c.c:c:c |
| C6H10Cl2Pd2 | |
| MFCD00044874 | |
| allylpalladium chloride dimer, bis allyl dichlorodipalladium, diallyldipalladium dichloride, palladium allyl chloride dimer, diallydichlorodipalladium, pi-allyl palladium chloride, allylpalladium ii chloride, bis chloro-pi-allylpalladium, allyl palladium chloride dimer, bis pi-allyl chloropalladium | |
| chloropalladium(1+);prop-1-ene |
Safety and Handling
GHS H Statement
H315-H319-H335
Causes skin irritation.
Causes serious eye irritation.
May cause respiratory irritation.
P264b-P280-P302+P352-P305+P351+P338-P332+P313-P362
H315-H319
EINECSNumber : 234-579-8
RTECSNumber : RT3510000
TSCA : No
storageNote1 : 2°C to 8°C
Recommended Storage : Keep cold; Store under Nitrogen
RUO – Research Use Only