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1-Bromo-3,3,3-trifluoroacetone, 97%
CAS: 431-35-6 | C3H2BrF3O | 190.95 g/mol
Supplier: Thermo Scientific Chemicals A1494806
Description
1-Bromo-3,3,3-trifluoroacetone is used in the preparation of 3-nonylthio-1,1,1-trifluoropropan-2-one and perfluoroalkylated trans-allylic alcohols. It is involved in the synthesis of cyclic tetrapeptides. Further, it reacts with potassium enolate of ethyl 4,4,4-trifluoroacetoacetate to produce ethyl 2,4-bis(trifluoromethyl)-4-hydroxydihydro-3-furoate.
This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.
Applications1-Bromo-3,3,3-trifluoroacetone is used in the preparation of 3-nonylthio-1,1,1-trifluoropropan-2-one and perfluoroalkylated trans-allylic alcohols. It is involved in the synthesis of cyclic tetrapeptides. Further, it reacts with potassium enolate of ethyl 4,4,4-trifluoroacetoacetate to produce ethyl 2,4-bis(trifluoromethyl)-4-hydroxydihydro-3-furoate.
Solubility
Immiscible with water.
Notes
Incompatible with strong oxidizing agents and bases.
Specifications
| 1-Bromo-3,3,3-trifluoroacetone | |
| <-80°C | |
| 85°C to 87°C | |
| Pungent | |
| 1.376 | |
| 5 g | |
| 1703387 | |
| Immiscible with water. | |
| FC(F)(F)C(=O)CBr | |
| 190.95 | |
| 190.95 |
| 431-35-6 | |
| 1.822 | |
| −2°C (28°F) | |
| C3H2BrF3O | |
| MFCD00039237 | |
| UN2924 | |
| 3-bromo-1,1,1-trifluoroacetone, 1-bromo-3,3,3-trifluoroacetone, bromotrifluoroacetone, 3-bromo-1,1,1-trifluoro-2-propanone, 3-bromo-1,1,1-trifluoropropanone, 1-bromo-3,3,3-trifluoro-2-propanone, 2-propanone, 3-bromo-1,1,1-trifluoro, 1,1,1-trifluoro-3-bromopropanone, 3-bromo-1,1,1-trifluoro-propan-2-one, bromotrifloroacetone | |
| ONZQYZKCUHFORE-UHFFFAOYSA-N | |
| 3-bromo-1,1,1-trifluoropropan-2-one | |
| 79008 | |
| 97% |
Chemical Identifiers
| 431-35-6 | |
| 190.95 | |
| ONZQYZKCUHFORE-UHFFFAOYSA-N | |
| 79008 | |
| FC(F)(F)C(=O)CBr |
| C3H2BrF3O | |
| MFCD00039237 | |
| 3-bromo-1,1,1-trifluoroacetone, 1-bromo-3,3,3-trifluoroacetone, bromotrifluoroacetone, 3-bromo-1,1,1-trifluoro-2-propanone, 3-bromo-1,1,1-trifluoropropanone, 1-bromo-3,3,3-trifluoro-2-propanone, 2-propanone, 3-bromo-1,1,1-trifluoro, 1,1,1-trifluoro-3-bromopropanone, 3-bromo-1,1,1-trifluoro-propan-2-one, bromotrifloroacetone | |
| 3-bromo-1,1,1-trifluoropropan-2-one |
Safety and Handling
GHS H Statement
H225-H314-H318
Highly flammable liquid and vapour.
Causes severe skin burns and eye damage.
Causes serious eye damage.
P210-P233-P240-P241-P242-P243-P260-P264b-P280-P301+P330+P331-P303+P361+P353-P304+P340-P305+P351+P338-P310-P363-P370+P378q-P501c
H225-H314
DOTInformation : Transport Hazard Class: 3; Packing Group: II; Proper Shipping Name: FLAMMABLE LIQUIDS, CORROSIVE, N.O.S.
EINECSNumber : 207-071-9
TSCA : No
Recommended Storage : Ambient temperatures
RUO – Research Use Only