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(1,3-Dioxolan-2-ylmethyl)triphenylphosphonium bromide, 98%

CAS: 52509-14-5 | C22H22BrO2P | 429.29 g/mol

$137.81 - $1777.12

Chemical Identifiers

CAS 52509-14-5
Molecular Formula C22H22BrO2P
Molecular Weight (g/mol) 429.29
MDL Number MFCD00011966
InChI Key FRHRVQQUICVJDG-UHFFFAOYSA-M
Synonym 1,3-dioxolan-2-ylmethyl triphenylphosphonium bromide, 1,3-dioxolan-2-yl methyl triphenylphosphonium bromide, 1,3-dioxolan-2-ylmethyl triphenylphosphanium bromide, phosphonium, 1,3-dioxolan-2-ylmethyl triphenyl-, bromide, 1,3-dioxolan-2-yl methyltriphenylphosphonium bromide, 1,3-dioxolan-2-ylmethyl triphenyl phosphanium bromide, 1,3-dioxolan-2-ylmethyl triphenyl phosphonium bromide, 1,3-dioxolan-2-ylmethyl triphenylphosphine, bromide, acmc-209kzyShow MoreShow Less
PubChem CID 2724194
IUPAC Name 1,3-dioxolan-2-ylmethyl(triphenyl)phosphanium;bromide
SMILES [Br-].C(C1OCCO1)[P+](C1=CC=CC=C1)(C1=CC=CC=C1)C1=CC=CC=C1
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AAA1888209
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Thermo Scientific Chemicals
A1888209
10 g
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AAA1888218
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Thermo Scientific Chemicals
A1888218
50 g
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AAA1888230
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Thermo Scientific Chemicals
A1888230
250 g
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Description

Description

It finds its applications as a reagent for Wittig olefinations with introduction of a 1,3-dioxolane moiety. It is applied as a reactant for the preparation of a ratiometric fluorescent probe for specific detection of cysteine over homocysteine and glutathione, for microwave-assisted synthesis of KN-93 as inhibitor of calmodulin kinase II, for the preparation of fluorinated spirobenzofuran piperidines as s1 receptor ligands, in the synthesis and antitumor agents, in regio-selective preparation of indole derivatives via rhodium-catalyzed domino hydroformylation/indolization.

This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.

Applications
It finds its applications as a reagent for Wittig olefinations with introduction of a 1,3-dioxolane moiety. It is applied as a reactant for the preparation of a ratiometric fluorescent probe for specific detection of cysteine over homocysteine and glutathione, for microwave-assisted synthesis of KN-93 as inhibitor of calmodulin kinase II, for the preparation of fluorinated spirobenzofuran piperidines as s1 receptor ligands, in the synthesis and antitumor agents, in regio-selective preparation of indole derivatives via rhodium-catalyzed domino hydroformylation/indolization.

Solubility
Soluble in water (20°C).

Notes
Hygroscopic. Store away from water/moisture and oxidizing agents. Store under inert gas. Keep the container tightly closed and place it in a cool, dry and well ventilated condition.
Specifications
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Safety and Handling

Safety and Handling

GHS H Statement
H315-H319-H335
Causes skin irritation.
Causes serious eye irritation.
May cause respiratory irritation.

P261-P264b-P270-P271-P280-P301+P312-P302+P352-P304+P340-P305+P351+P338-P312-P330-P332+P313-P362-P501c

H302+H312+H332-H315-H319-H335

EINECSNumber : 257-977-3

TSCA : No

Recommended Storage : Keep cold

SDS
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RUO – Research Use Only