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1,3-Dibromobenzene, 97+%
CAS: 108-36-1 | C6H4Br2 | 235.91 g/mol
Supplier: Thermo Scientific Chemicals A1272322
Description
1,3-Dibromobenzene is used in Suzuki coupling reaction for the preparation of [n]metacyclophanes. It is used to prepare 5-(3-bromo-phenyl)-2,4-di-tert-butoxy-pyrimidine using Pd(0) (PPh3)4 as a reagent. Further, it undergoes solid-supported potassium fluoride-aluminum oxide palladium-catalyzed polyarylation reaction with phenyl boronic acid to get conjugated polyaryls.
This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.
Applications1,3-Dibromobenzene is used in Suzuki coupling reaction for the preparation of [n]metacyclophanes. It is used to prepare 5-(3-bromo-phenyl)-2,4-di-tert-butoxy-pyrimidine using Pd(0) (PPh3)4 as a reagent. Further, it undergoes solid-supported potassium fluoride-aluminum oxide palladium-catalyzed polyarylation reaction with phenyl boronic acid to get conjugated polyaryls.
Solubility
Immiscible with water.
Notes
Incompatible with strong oxidizing agents.
Specifications
| 1,3-Dibromobenzene | |
| -7°C | |
| 219°C to 220°C | |
| 97% | |
| C6H4Br2 | |
| MFCD00000078 | |
| UN3082 | |
| m-dibromobenzene, benzene, 1,3-dibromo, benzene, m-dibromo, unii-74ef6kh8tc, 1,3-dibromo-benzene, 74ef6kh8tc, 1,3-dibromo benzene, 3,5-dibromobenzene, 1,3-dibrormobenzene, 1, 3-dibromobenzene | |
| JSRLURSZEMLAFO-UHFFFAOYSA-N | |
| 1,3-dibromobenzene | |
| 7927 | |
| 235.91 | |
| Liquid |
| 108-36-1 | |
| 1.955 | |
| 93°C (199°F) | |
| Odorless | |
| 1.608 | |
| 100 g | |
| 1904538 | |
| Immiscible with water. | |
| BrC1=CC(Br)=CC=C1 | |
| 235.91 | |
| CHEBI:37151 | |
| ≥97% |
Chemical Identifiers
| 108-36-1 | |
| 235.91 | |
| JSRLURSZEMLAFO-UHFFFAOYSA-N | |
| 7927 | |
| 1,3-dibromobenzene |
| C6H4Br2 | |
| MFCD00000078 | |
| m-dibromobenzene, benzene, 1,3-dibromo, benzene, m-dibromo, unii-74ef6kh8tc, 1,3-dibromo-benzene, 74ef6kh8tc, 1,3-dibromo benzene, 3,5-dibromobenzene, 1,3-dibrormobenzene, 1, 3-dibromobenzene | |
| CHEBI:37151 | |
| BrC1=CC(Br)=CC=C1 |
Safety and Handling
GHS H Statement
H315-H319-H227
Causes skin irritation.
Causes serious eye irritation.
Combustible liquid.
P210-P235-P261-P264b-P271-P280-P302+P352-P304+P340-P305+P351+P338-P312-P332+P313-P362-P370+P378q-P501c
H227-H315-H319-H335
DOTInformation : Transport Hazard Class: 9; Packing Group: III; Proper Shipping Name: ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S.
EINECSNumber : 203-574-2
RTECSNumber : CZ1790000
TSCA : Yes
Recommended Storage : Ambient temperatures
RUO – Research Use Only