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Triphenylcarbenium tetrafluoroborate, 97%

CAS: 341-02-6 | C19H15BF4 | 330.133 g/mol

$121.10 - $1777.66

Chemical Identifiers

CAS 341-02-6
Molecular Formula C19H15BF4
Molecular Weight (g/mol) 330.133
MDL Number MFCD00013120
InChI Key VQXBOEYKSVVPSP-UHFFFAOYSA-N
Synonym triphenylcarbenium tetrafluoroborate, trityl tetrafluoroborate, tritylium tetrafluoroborate, triphenylmethylium tetrafluoroborate, diphenylmethylbenzene tetrafluoroborate, trityl fluoroborate, triphenylmethyl fluoroborate, triphenylcarbonium tetrafluoroborate, methylium, triphenyl-, tetrafluoroborate 1-, methylium, triphenyl-, tetrafluoroborate 1-1:1
PubChem CID 2723955
IUPAC Name diphenylmethylbenzene;tetrafluoroborate
SMILES [B-](F)(F)(F)F.C1=CC=C(C=C1)[C+](C2=CC=CC=C2)C3=CC=CC=C3
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AAA1294909
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Thermo Scientific Chemicals
A1294909
10 g
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AAA1294918
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Thermo Scientific Chemicals
A1294918
50 g
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AAA1294930
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A1294930
250 g
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Description

Description

It is applied in the abstraction of the-H atom of alcohols and their O-substituted derivatives results in oxidation to the ketones and in the oxidation of TMS ethers to ketones, secondary alcohols to ketones, and secondary diols to ?-hydroxy ketones. It is applied as a reactant involved in the synthesis of substituted dihydroazulene photo switches, carbene-based Lewis pairs for hydrogen activation, 1,3-Dipolar cycloaddition reactions for preparation of α-amino-β-hydroxy esters, oxidation of allenic compounds, Mukaiyama aldol addition reactions and ionic hydrogenation as a counteranion and ligand source.

This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.

Applications
It is applied in the abstraction of the ɑ-H atom of alcohols and their O-substituted derivatives results in oxidation to the ketones and in the oxidation of TMS ethers to ketones, secondary alcohols to ketones, and secondary diols to ɑ-hydroxy ketones. It is applied as a reactant involved in the synthesis of substituted dihydroazulene photo switches, carbene-based Lewis pairs for hydrogen activation, 1,3-Dipolar cycloaddition reactions for preparation of α-amino-β-hydroxy esters, oxidation of allenic compounds, Mukaiyama aldol addition reactions and ionic hydrogenation as a counteranion and ligand source.

Solubility
Insoluble in water. Soluble in methanol.

Notes
Moisture sensitive. Store away from bases, water/moisture, heat and oxidizing agents. Keep the container tightly closed and place it in a cool, dry and well ventilated condition. Store under inert gas. Keep it refrigerated.
Specifications

Chemical Identifiers

341-02-6
330.133
VQXBOEYKSVVPSP-UHFFFAOYSA-N
2723955
[B-](F)(F)(F)F.C1=CC=C(C=C1)[C+](C2=CC=CC=C2)C3=CC=CC=C3
C19H15BF4
MFCD00013120
triphenylcarbenium tetrafluoroborate, trityl tetrafluoroborate, tritylium tetrafluoroborate, triphenylmethylium tetrafluoroborate, diphenylmethylbenzene tetrafluoroborate, trityl fluoroborate, triphenylmethyl fluoroborate, triphenylcarbonium tetrafluoroborate, methylium, triphenyl-, tetrafluoroborate 1-, methylium, triphenyl-, tetrafluoroborate 1-1:1
diphenylmethylbenzene;tetrafluoroborate

Specifications

341-02-6
Odorless
(C6H5)3CBF4
10 g
5085649
triphenylcarbenium tetrafluoroborate, trityl tetrafluoroborate, tritylium tetrafluoroborate, triphenylmethylium tetrafluoroborate, diphenylmethylbenzene tetrafluoroborate, trityl fluoroborate, triphenylmethyl fluoroborate, triphenylcarbonium tetrafluoroborate, methylium, triphenyl-, tetrafluoroborate 1-, methylium, triphenyl-, tetrafluoroborate 1-1:1
VQXBOEYKSVVPSP-UHFFFAOYSA-N
diphenylmethylbenzene;tetrafluoroborate
2723955
98%
∼207°C (decomposition)
C19H15BF4
MFCD00013120
UN3261
Moisture sensitive
Insoluble in water. Soluble in methanol.
[B-](F)(F)(F)F.C1=CC=C(C=C1)[C+](C2=CC=CC=C2)C3=CC=CC=C3
330.133
330.13
Triphenylcarbenium tetrafluoroborate
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Safety and Handling

Safety and Handling

GHS H Statement
H314-H318
Causes severe skin burns and eye damage.
Causes serious eye damage.

P260-P264b-P271-P280-P301+P330+P331-P303+P361+P353-P304+P340-P305+P351+P338-P310-P363-P501c

H314-H335

DOTInformation : Transport Hazard Class: 8; Packing Group: II; Proper Shipping Name: CORROSIVE SOLID, ACIDIC, ORGANIC, N.O.S.

EINECSNumber : 206-433-3

TSCA : Yes

Recommended Storage : Keep cold; Store under Nitrogen

SDS
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RUO – Research Use Only