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Triphenylcarbenium tetrafluoroborate, 97%
CAS: 341-02-6 | C19H15BF4 | 330.133 g/mol
$121.10 - $1777.66
Chemical Identifiers
| CAS | 341-02-6 |
|---|---|
| Molecular Formula | C19H15BF4 |
| Molecular Weight (g/mol) | 330.133 |
| MDL Number | MFCD00013120 |
| InChI Key | VQXBOEYKSVVPSP-UHFFFAOYSA-N |
| Synonym | triphenylcarbenium tetrafluoroborate, trityl tetrafluoroborate, tritylium tetrafluoroborate, triphenylmethylium tetrafluoroborate, diphenylmethylbenzene tetrafluoroborate, trityl fluoroborate, triphenylmethyl fluoroborate, triphenylcarbonium tetrafluoroborate, methylium, triphenyl-, tetrafluoroborate 1-, methylium, triphenyl-, tetrafluoroborate 1-1:1 |
| PubChem CID | 2723955 |
| IUPAC Name | diphenylmethylbenzene;tetrafluoroborate |
| SMILES | [B-](F)(F)(F)F.C1=CC=C(C=C1)[C+](C2=CC=CC=C2)C3=CC=CC=C3 |
| Catalog Number | Mfr. No. | Quantity | Price | Quantity | |||||
|---|---|---|---|---|---|---|---|---|---|
| Catalog Number | Mfr. No. | Quantity | Price | Quantity | |||||
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AAA1294909
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Thermo Scientific Chemicals
A1294909 |
10 g |
Each for $121.10
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AAA1294918
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Thermo Scientific Chemicals
A1294918 |
50 g |
Each for $458.97
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AAA1294930
|
Thermo Scientific Chemicals
A1294930 |
250 g |
Each for $1,777.66
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Description
It is applied in the abstraction of the-H atom of alcohols and their O-substituted derivatives results in oxidation to the ketones and in the oxidation of TMS ethers to ketones, secondary alcohols to ketones, and secondary diols to ?-hydroxy ketones. It is applied as a reactant involved in the synthesis of substituted dihydroazulene photo switches, carbene-based Lewis pairs for hydrogen activation, 1,3-Dipolar cycloaddition reactions for preparation of α-amino-β-hydroxy esters, oxidation of allenic compounds, Mukaiyama aldol addition reactions and ionic hydrogenation as a counteranion and ligand source.
This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.
ApplicationsIt is applied in the abstraction of the É-H atom of alcohols and their O-substituted derivatives results in oxidation to the ketones and in the oxidation of TMS ethers to ketones, secondary alcohols to ketones, and secondary diols to É-hydroxy ketones. It is applied as a reactant involved in the synthesis of substituted dihydroazulene photo switches, carbene-based Lewis pairs for hydrogen activation, 1,3-Dipolar cycloaddition reactions for preparation of α-amino-β-hydroxy esters, oxidation of allenic compounds, Mukaiyama aldol addition reactions and ionic hydrogenation as a counteranion and ligand source.
Solubility
Insoluble in water. Soluble in methanol.
Notes
Moisture sensitive. Store away from bases, water/moisture, heat and oxidizing agents. Keep the container tightly closed and place it in a cool, dry and well ventilated condition. Store under inert gas. Keep it refrigerated.
Chemical Identifiers
| 341-02-6 | |
| 330.133 | |
| VQXBOEYKSVVPSP-UHFFFAOYSA-N | |
| 2723955 | |
| [B-](F)(F)(F)F.C1=CC=C(C=C1)[C+](C2=CC=CC=C2)C3=CC=CC=C3 |
| C19H15BF4 | |
| MFCD00013120 | |
| triphenylcarbenium tetrafluoroborate, trityl tetrafluoroborate, tritylium tetrafluoroborate, triphenylmethylium tetrafluoroborate, diphenylmethylbenzene tetrafluoroborate, trityl fluoroborate, triphenylmethyl fluoroborate, triphenylcarbonium tetrafluoroborate, methylium, triphenyl-, tetrafluoroborate 1-, methylium, triphenyl-, tetrafluoroborate 1-1:1 | |
| diphenylmethylbenzene;tetrafluoroborate |
Specifications
| 341-02-6 | |
| Odorless | |
| (C6H5)3CBF4 | |
| 10 g | |
| 5085649 | |
| triphenylcarbenium tetrafluoroborate, trityl tetrafluoroborate, tritylium tetrafluoroborate, triphenylmethylium tetrafluoroborate, diphenylmethylbenzene tetrafluoroborate, trityl fluoroborate, triphenylmethyl fluoroborate, triphenylcarbonium tetrafluoroborate, methylium, triphenyl-, tetrafluoroborate 1-, methylium, triphenyl-, tetrafluoroborate 1-1:1 | |
| VQXBOEYKSVVPSP-UHFFFAOYSA-N | |
| diphenylmethylbenzene;tetrafluoroborate | |
| 2723955 | |
| 98% |
| ∼207°C (decomposition) | |
| C19H15BF4 | |
| MFCD00013120 | |
| UN3261 | |
| Moisture sensitive | |
| Insoluble in water. Soluble in methanol. | |
| [B-](F)(F)(F)F.C1=CC=C(C=C1)[C+](C2=CC=CC=C2)C3=CC=CC=C3 | |
| 330.133 | |
| 330.13 | |
| Triphenylcarbenium tetrafluoroborate |
Safety and Handling
GHS H Statement
H314-H318
Causes severe skin burns and eye damage.
Causes serious eye damage.
P260-P264b-P271-P280-P301+P330+P331-P303+P361+P353-P304+P340-P305+P351+P338-P310-P363-P501c
H314-H335
DOTInformation : Transport Hazard Class: 8; Packing Group: II; Proper Shipping Name: CORROSIVE SOLID, ACIDIC, ORGANIC, N.O.S.
EINECSNumber : 206-433-3
TSCA : Yes
Recommended Storage : Keep cold; Store under Nitrogen
RUO – Research Use Only