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Triisopropylsilane, 98%
CAS: 6485-79-6 | C9H22Si | 158.36 g/mol
Supplier: Thermo Scientific Chemicals L0958522
Description
Triisopropylsilane is used as a protecting group in peptide synthesis and is also used as a reducing agent for the selective reduction of anomeric C-phenyl ketals. It is used in the selective silylation of primary hydroxyl groups without affecting the secondary hydroxyl group. It is used in the preparation of anti-1,2-diols catalyzed by a Ni(O) N-heterocyclic carbine complex with high diastereoselectivity.
This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.
ApplicationsTriisopropylsilane is used as a protecting group in peptide synthesis and is also used as a reducing agent for the selective reduction of anomeric C-phenyl ketals. It is used in the selective silylation of primary hydroxyl groups without affecting the secondary hydroxyl group. It is used in the preparation of anti-1,2-diols catalyzed by a Ni(O) N-heterocyclic carbine complex with high diastereoselectivity.
Solubility
Immiscible with water.
Notes
Moisture sensitive. Keep the container tightly closed in a dry and well-ventilated place. Incompatible with strong acids and strong oxidizing agents.
Specifications
| 166°C | |
| 6485-79-6 | |
| C9H22Si | |
| MFCD00009657 | |
| 1733718 | |
| triisopropylsilane, tris propan-2-yl silane, triisopropyl silane, tri propan-2-yl silicon, tri-isopropylsilyl radical, triisopropylsilyl, tri-iso-propylsilane, ambotzrl-1102, pubchem12855 | |
| YDJXDYKQMRNUSA-UHFFFAOYSA-N | |
| tri(propan-2-yl)silicon | |
| 6327611 | |
| 98% | |
| 1.434 |
| Triisopropylsilane | |
| 100 g | |
| [(CH3)2CH]3SiH | |
| UN1993 | |
| 35°C (95°F) | |
| Immiscible with water. | |
| CC(C)[SiH](C(C)C)C(C)C | |
| 158.36 | |
| 158.36 | |
| Mild | |
| 0.773 |
Chemical Identifiers
| 6485-79-6 | |
| 158.36 | |
| YDJXDYKQMRNUSA-UHFFFAOYSA-N | |
| 6327611 |
| C9H22Si | |
| MFCD00009657 | |
| triisopropylsilane, tris propan-2-yl silane, triisopropyl silane, tri propan-2-yl silicon, tri-isopropylsilyl radical, triisopropylsilyl, tri-iso-propylsilane, ambotzrl-1102, pubchem12855 | |
| CC(C)[SiH](C(C)C)C(C)C |
Safety and Handling
GHS H Statement
H226-H315-H319-H335
Flammable liquid and vapor.
Causes skin irritation.
Causes serious eye irritation.
May cause respiratory irritation.
P210-P233-P235-P240-P241-P242-P243-P261-P264b-P271-P280-P303+P361+P353-P304+P340-P305+P351+P338-P312-P332+P313-P363-P370+P378q-P501c
H226-H315-H319-H335
DOTInformation : Transport Hazard Class: 3; Packing Group: III; Proper Shipping Name: FLAMMABLE LIQUIDS, N.O.S.
TSCA : No
Recommended Storage : Ambient temperatures
RUO – Research Use Only