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  7. Triisopropylsilane, 98%

Triisopropylsilane, 98%

Catalog No. AAL0958506
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Quantity:
5 g
25 g
100 g
Catalog No. Quantity
AAL0958506 5 g
AAL0958514 25 g
AAL0958522 100 g
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Catalog No. AAL0958506

Supplier: Thermo Scientific Chemicals L0958506

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Description

CAS: 6485-79-6 | C9H22Si | 158.36 g/mol

Triisopropylsilane is used as a protecting group in peptide synthesis and is also used as a reducing agent for the selective reduction of anomeric C-phenyl ketals. It is used in the selective silylation of primary hydroxyl groups without affecting the secondary hydroxyl group. It is used in the preparation of anti-1,2-diols catalyzed by a Ni(O) N-heterocyclic carbine complex with high diastereoselectivity.

This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.

Applications
Triisopropylsilane is used as a protecting group in peptide synthesis and is also used as a reducing agent for the selective reduction of anomeric C-phenyl ketals. It is used in the selective silylation of primary hydroxyl groups without affecting the secondary hydroxyl group. It is used in the preparation of anti-1,2-diols catalyzed by a Ni(O) N-heterocyclic carbine complex with high diastereoselectivity.

Solubility
Immiscible with water.

Notes
Moisture sensitive. Keep the container tightly closed in a dry and well-ventilated place. Incompatible with strong acids and strong oxidizing agents.

Chemical Identifiers

CAS 6485-79-6
Molecular Formula C9H22Si
Molecular Weight (g/mol) 158.36
MDL Number MFCD00009657
InChI Key YDJXDYKQMRNUSA-UHFFFAOYSA-N
Synonym triisopropylsilane, tris propan-2-yl silane, triisopropyl silane, tri propan-2-yl silicon, tri-isopropylsilyl radical, triisopropylsilyl, tri-iso-propylsilane, ambotzrl-1102, pubchem12855
PubChem CID 6327611
SMILES CC(C)[SiH](C(C)C)C(C)C

Specifications

Boiling Point 166°C
Quantity 5 g
Linear Formula [(CH3)2CH]3SiH
UN Number UN1993
Beilstein 1733718
Flash Point 35°C (95°F)
Solubility Information Immiscible with water.
IUPAC Name tris(propan-2-yl)silane
Formula Weight 158.36
Percent Purity 98%
Odor Mild
Refractive Index 1.434
Density 0.773
Chemical Name or Material Triisopropylsilane
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Safety and Handling

Hazard Category H226-H315-H319-H335
Hazard Statement GHS H Statement
H226-H315-H319-H335
Flammable liquid and vapor.
Causes skin irritation.
Causes serious eye irritation.
May cause respiratory irritation.
Precautionary Statement P210-P233-P235-P240-P241-P242-P243-P261-P264b-P271-P280-P303+P361+P353-P304+P340-P305+P351+P338-P312-P332+P313-P363-P370+P378q-P501c
DOTInformation Transport Hazard Class: 3; Packing Group: III; Proper Shipping Name: FLAMMABLE LIQUIDS, N.O.S.
TSCA No
Recommended Storage Ambient temperatures

RUO – Research Use Only