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Triethylamine trihydrofluoride, ca 37% HF, Thermo Scientific Chemicals
$52.60 - $406.01
Chemical Identifiers
| CAS | 73602-61-6 |
|---|---|
| Molecular Formula | C6H18F3N |
| Molecular Weight (g/mol) | 161.212 |
| MDL Number | MFCD00043294 |
| InChI Key | IKGLACJFEHSFNN-UHFFFAOYSA-N |
| Synonym | triethylamine trihydrofluoride, n,n-diethylethanamine trihydrofluoride, triethylammonium fluoride, ethanamine, n,n-diethyl-, trihydrofluoride, triethylamine trishydrofluoride, hydrogen fluoride in triethylamine, hf in triethylamine, triethylaminetrihydrofluoride, hydrogen fluoride triethylamine, ethanamine, n,n-diethyl-, hydrofluoride 1:3 |
| PubChem CID | 175505 |
| IUPAC Name | N,N-diethylethanamine;trihydrofluoride |
| SMILES | CCN(CC)CC.F.F.F |
| Catalog Number | Mfr. No. | Quantity | Price | Quantity | |||||
|---|---|---|---|---|---|---|---|---|---|
| Catalog Number | Mfr. No. | Quantity | Price | Quantity | |||||
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AAL1441706
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Thermo Scientific Chemicals
L1441706 |
5 g |
Each for $52.60
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AAL1441714
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Thermo Scientific Chemicals
L1441714 |
25 g |
Each for $159.23
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AAL1441722
|
Thermo Scientific Chemicals
L1441722 |
100 g |
Each for $406.01
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Description
Triethylamine trihydrofluoride acts as a mild and selective fluorinating agent used in the synthesis of acid fluorides and alkyl fluorides. It is also used in the synthesis of vicinal difluorides from epoxides, 3-fluoroazetidine. It is utilized as a selective reagent for the cleavage of O-silyl groups in carbohydrates, nucleotides and cyanohydrins. It is actively involved in the electrochemical fluorodeiodination of alkyl iodides and fluorodesilylation in beta-lactams.
This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.
ApplicationsTriethylamine trihydrofluoride acts as a mild and selective fluorinating agent used in the synthesis of acid fluorides and alkyl fluorides. It is also used in the synthesis of vicinal difluorides from epoxides, 3-fluoroazetidine. It is utilized as a selective reagent for the cleavage of O-silyl groups in carbohydrates, nucleotides and cyanohydrins. It is actively involved in the electrochemical fluorodeiodination of alkyl iodides and fluorodesilylation in beta-lactams.
Solubility
Miscible with water, chloroform and hexanes.
Notes
Hygroscopic. Incompatible with strong oxidizing agents and glass.
Chemical Identifiers
| 73602-61-6 | |
| 161.212 | |
| IKGLACJFEHSFNN-UHFFFAOYSA-N | |
| 175505 | |
| CCN(CC)CC.F.F.F |
| C6H18F3N | |
| MFCD00043294 | |
| triethylamine trihydrofluoride, n,n-diethylethanamine trihydrofluoride, triethylammonium fluoride, ethanamine, n,n-diethyl-, trihydrofluoride, triethylamine trishydrofluoride, hydrogen fluoride in triethylamine, hf in triethylamine, triethylaminetrihydrofluoride, hydrogen fluoride triethylamine, ethanamine, n,n-diethyl-, hydrofluoride 1:3 | |
| N,N-diethylethanamine;trihydrofluoride |
Specifications
| 73602-61-6 | |
| 0.99 | |
| 87°C (188°F) | |
| 1.3915 | |
| MFCD00043294 | |
| UN1790 | |
| Hygroscopic | |
| Miscible with water,chloroform and hexanes. | |
| CCN(CC)CC.F.F.F | |
| 161.212 | |
| 161.21 | |
| ≈37% HF |
| -29°C | |
| 70°C (15 mmHg) | |
| C6H18F3N | |
| (CH3CH2)3N·3HF | |
| 5 g | |
| 5522945 | |
| triethylamine trihydrofluoride, n,n-diethylethanamine trihydrofluoride, triethylammonium fluoride, ethanamine, n,n-diethyl-, trihydrofluoride, triethylamine trishydrofluoride, hydrogen fluoride in triethylamine, hf in triethylamine, triethylaminetrihydrofluoride, hydrogen fluoride triethylamine, ethanamine, n,n-diethyl-, hydrofluoride 1:3 | |
| IKGLACJFEHSFNN-UHFFFAOYSA-N | |
| N,N-diethylethanamine;trihydrofluoride | |
| 175505 | |
| Triethylamine trihydrofluoride |
Safety and Handling
GHS H Statement
H300-H310-H330-H314-H318-H227
Fatal if swallowed.
Fatal in contact with skin.
Fatal if inhaled.
Causes severe skin burns and eye damage.
Causes serious eye damage.
Combustible liquid.
P210-P235-P260-P262-P264b-P270-P271-P280-P284-P303+P361+P353-P304+P340-P305+P351+P338-P310-P330-P331-P363-P370+P378q-P501c
H227-H300+H310+H330-H314-H335
DOTInformation : Transport Hazard Class: 8; Packing Group: II; Proper Shipping Name: HYDROFLUORIC ACID
EINECSNumber : 277-550-5
TSCA : Yes
Recommended Storage : Ambient temperatures; Store under Nitrogen
RUO – Research Use Only