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Triethyl phosphite, 98%, Thermo Scientific Chemicals

Supplier:  Thermo Scientific Chemicals L00339AE

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Catalog No. AAL00339AE


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Description

Description

Triethyl phosphite is used as a ligand in organometallic chemistry and as a reagent in organic synthesis. It is used as reference to phosphoric acid standard in 31P NMR spectroscopy. It acts as a reducing agent to prepare 2-phenylindazole from o-nitrobenzylidineaniline as well as reacts with electrophiles to get phosphonates. It forms a stable complex with copper(I) iodide. It finds application in a modified Staudinger reaction for the alkyl bromide to an amine through the azide. Further, it is also used in the preparation of 3-phenyl-2-substituted indoles by reacting with beta-nitro styrenes.

This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.

Applications
Triethyl phosphite is used as a ligand in organometallic chemistry and as a reagent in organic synthesis. It is used as reference to phosphoric acid standard in 31P NMR spectroscopy. It acts as a reducing agent to prepare 2-phenylindazole from o-nitrobenzylidineaniline as well as reacts with electrophiles to get phosphonates. It forms a stable complex with copper(I) iodide. It finds application in a modified Staudinger reaction for the alkyl bromide to an amine through the azide. Further, it is also used in the preparation of 3-phenyl-2-substituted indoles by reacting with beta-nitro styrenes.

Solubility
Miscible with alcohol and ether. Immiscible with water.

Notes
Air and moisture sensitive. Incompatible with strong oxidizing agents and strong bases.
Specifications

Specifications

Triethyl phosphite
-112°C
155°C to 157°C
Unpleasant
1.413
100 mL
956578
phosphorous acid, triethyl ester, triethoxyphosphine, ethyl phosphite, eto 3p, triethylphosphite, phosphorous acid triethyl ester, fosforyn trojetylowy czech, unii-6b2r04s55g, hsdb 895, p oet 3, c2h5o 3p
BDZBKCUKTQZUTL-UHFFFAOYSA-N
triethyl phosphite
31215
98%
122-52-1
0.958
43°C (109°F)
C6H15O3P
MFCD00009084
UN2323
Air and moisture sensitive
Miscible with alcohol and ether. Immiscible with water.
CCOP(OCC)OCC
166.157
166.16

Chemical Identifiers

122-52-1
166.157
BDZBKCUKTQZUTL-UHFFFAOYSA-N
31215
CCOP(OCC)OCC
C6H15O3P
MFCD00009084
phosphorous acid, triethyl ester, triethoxyphosphine, ethyl phosphite, eto 3p, triethylphosphite, phosphorous acid triethyl ester, fosforyn trojetylowy czech, unii-6b2r04s55g, hsdb 895, p oet 3, c2h5o 3p
triethyl phosphite
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Safety and Handling

Safety and Handling

GHS H Statement
H226-H332-H319-H317
Flammable liquid and vapor.
Harmful if inhaled.
Causes serious eye irritation.
May cause an allergic skin reaction.

P210-P233-P240-P241-P242-P243-P280-P303+P361+P353-P370+P378q-P501c

H226

DOTInformation : Transport Hazard Class: 3; Packing Group: III; Proper Shipping Name: TRIETHYL PHOSPHITE

EINECSNumber : 204-552-5

RTECSNumber : TH1130000

TSCA : Yes

Recommended Storage : Ambient temperatures; Store under Argon

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