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tert-Butylmagnesium chloride, 1M in MeTHF

Catalog No. AAH51164AE
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AAH51164AE 100 mL
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Catalog No. AAH51164AE Supplier Thermo Scientific Chemicals Supplier No. H51164AE
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CAS: 677-22-5 | C4H9ClMg | 116.87 g/mol

tert-Butylmagnesium chloride is a Grignard reagent used in organic synthesis. It is also involved in copper-catalyzed cross-coupling reaction with primary-alkyl halides.

This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.

Applications
tert-Butylmagnesium chloride is a Grignard reagent used in organic synthesis. It is also involved in copper-catalyzed cross-coupling reaction with primary-alkyl halides.

Solubility
Miscible with alcohol and water.

Notes
Air and moisture sensitive. Incompatible with oxidizing agents and bases.

Chemical Identifiers

CAS 677-22-5
Molecular Formula C4H9ClMg
Molecular Weight (g/mol) 116.87
MDL Number MFCD00000465
InChI Key ZDRJSYVHDMFHSC-UHFFFAOYSA-M
Synonym tert-butylmagnesium chloride, tert-butylmagnesiumchloride, t-butylmagnesium chloride, t-butyl magnesium chloride, tert-butyl chloro magnesium, magnesium, chloro 1,1-dimethylethyl, tert-butylmagnesium chloride solution, 1.0 m in thf, tbumgcl, tert-bumgcl, t-bumgcl
PubChem CID 2724198
IUPAC Name magnesium;2-methylpropane;chloride
SMILES CC(C)(C)[Mg]Cl

Specifications

Linear Formula (CH3)3CMgCl
Quantity 100 mL
UN Number UN3399
Sensitivity Air and moisture sensitive
Solubility Information Miscible with alcohol and water.
Formula Weight 116.87
Concentration or Composition (by Analyte or Components) 1M in MeTHF
Chemical Name or Material tert-Butylmagnesium chloride
Hazard Category H225-H260-H302-H314-H335
Hazard Statement GHS H Statement
H225-H261-H314
Highly flammable liquid and vapor.
In contact with water releases flammable gas.
Causes severe skin burns and eye damage.
Precautionary Statement P210-P223-P231+P232-P233-P235-P240-P241-P242-P243-P260-P264b-P270-P271-P280-P303+P361+P353-P304+P340-P305+P351+P338-P310-P330-P331-P335+P334-P363-P370+P378q-P501c
DOTInformation Transport Hazard Class: 4.3; Packing Group: II; Proper Shipping Name: ORGANOMETALLIC SUBSTANCE, LIQUID, WATER-REACTIVE, FLAMMABLE
TSCA No
Recommended Storage Ambient temperatures; Store under Argon

RUO – Research Use Only