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Sulfur trioxide-pyridine complex, 98%, active SO3 ca 48-50%
CAS: 26412-87-3 | C5H5NO3S | 159.16 g/mol
$52.44 - $1239.25
Chemical Identifiers
| CAS | 26412-87-3 |
|---|---|
| Molecular Formula | C5H5NO3S |
| Molecular Weight (g/mol) | 159.16 |
| MDL Number | MFCD00012437 |
| InChI Key | UDYFLDICVHJSOY-UHFFFAOYSA-N |
| Synonym | pyridine sulfur trioxide, sulfur trioxide pyridine complex, pyridine; sulfur trioxide, pyridine sulfotrioxide, pyridine compound with sulfur trioxide 1:1, sulfur trioxide, compd. with pyridine, pyridine-sulfur trioxide complex, active sulfure trioxide, sulfur trioxide-pyridine, pyridine-sulfur trioxide |
| PubChem CID | 168533 |
| SMILES | O=S(=O)=O.C1=CC=NC=C1 |
| Catalog Number | Mfr. No. | Quantity | Price | Quantity | |||||
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| Catalog Number | Mfr. No. | Quantity | Price | Quantity | |||||
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AAA1220209
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Thermo Scientific Chemicals
A1220209 |
10 g |
Each for $52.44
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AAA1220218
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Thermo Scientific Chemicals
A1220218 |
50 g |
Each for $111.38
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AAA1220230
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Thermo Scientific Chemicals
A1220230 |
250 g |
Each for $455.45
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AAA122020B
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Thermo Scientific Chemicals
A122020B |
1000 g |
Each for $1,239.25
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Description
Sulfur trioxide-pyridine complex is used for sulfations of alcohols, sulfonations, deoxygenations and other reductions, oxidations with dimethyl sulfoxide. It is also used as a source of sulfur trioxide especially in the preparation of sulfate esters. Further, it is used as an activating electrophile in a Parikh-Doering oxidation. In addition to this, it is also used in the preparation and anticoagulation test of sulfated silk fibroin.
This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.
ApplicationsSulfur trioxide-pyridine complex is used for sulfations of alcohols, sulfonations, deoxygenations and other reductions, oxidations with dimethyl sulfoxide. It is also used as a source of sulfur trioxide especially in the preparation of sulfate esters. Further, it is used as an activating electrophile in a Parikh-Doering oxidation. In addition to this, it is also used in the preparation and anticoagulation test of sulfated silk fibroin.
Solubility
Soluble in polar organic solvents.
Notes
Moisture sensitive. Incompatible with strong oxidizing agents.
Chemical Identifiers
| 26412-87-3 | |
| 159.16 | |
| UDYFLDICVHJSOY-UHFFFAOYSA-N | |
| 168533 |
| C5H5NO3S | |
| MFCD00012437 | |
| pyridine sulfur trioxide, sulfur trioxide pyridine complex, pyridine; sulfur trioxide, pyridine sulfotrioxide, pyridine compound with sulfur trioxide 1:1, sulfur trioxide, compd. with pyridine, pyridine-sulfur trioxide complex, active sulfure trioxide, sulfur trioxide-pyridine, pyridine-sulfur trioxide | |
| O=S(=O)=O.C1=CC=NC=C1 |
Specifications
| 26412-87-3 | |
| C5H5NO3S | |
| 10 g | |
| 3704116 | |
| pyridine sulfur trioxide, sulfur trioxide pyridine complex, pyridine; sulfur trioxide, pyridine sulfotrioxide, pyridine compound with sulfur trioxide 1:1, sulfur trioxide, compd. with pyridine, pyridine-sulfur trioxide complex, active sulfure trioxide, sulfur trioxide-pyridine, pyridine-sulfur trioxide | |
| UDYFLDICVHJSOY-UHFFFAOYSA-N | |
| pyridine;sulfur trioxide | |
| 168533 | |
| 98% |
| ∼155°C to 165°C | |
| MFCD00012437 | |
| UN3261 | |
| Moisture sensitive | |
| Soluble in polar organic solvents. | |
| O=S(=O)=O.C1=CC=NC=C1 | |
| 159.16 | |
| 159.16 | |
| Sulfur trioxide-pyridine complex, Active SO3 ≈48 to 50% |
Safety and Handling
GHS H Statement
H314-H318-H302
Causes severe skin burns and eye damage.
Causes serious eye damage.
Harmful if swallowed.
P264b-P270-P280-P301+P312-P302+P352-P305+P351+P338-P330-P332+P313-P362-P501c
H302-H315-H319
DOTInformation : Transport Hazard Class: 8; Packing Group: II; Proper Shipping Name: CORROSIVE SOLID, ACIDIC, ORGANIC, N.O.S.
EINECSNumber : 247-683-3
TSCA : Yes
Recommended Storage : Ambient temperatures; Store under Nitrogen
RUO – Research Use Only