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Phenyl phosphorodichloridate, 97%, Thermo Scientific Chemicals
$56.78 - $575.25
Chemical Identifiers
CAS | 770-12-7 |
---|---|
Molecular Formula | C6H5Cl2O2P |
Molecular Weight (g/mol) | 210.978 |
MDL Number | MFCD00002067 |
InChI Key | TXFOLHZMICYNRM-UHFFFAOYSA-N |
Synonym | phenyl dichlorophosphate, phenyl phosphorodichloridate, dichlorophenoxyphosphine oxide, phosphorodichloridic acid, phenyl ester, phenylphosphoric dichloride, phenyl phosphorodichlorodate, phenoxydichlorophosphine oxide, phenyldichlorophosphate, phenoxyphosphoryl dichloride, phosphoroyl dichloride phenyl ester |
PubChem CID | 13038 |
IUPAC Name | dichlorophosphoryloxybenzene |
SMILES | C1=CC=C(C=C1)OP(=O)(Cl)Cl |
Catalog Number | Mfr. No. | Quantity | Price | Quantity | |||||
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Catalog Number | Mfr. No. | Quantity | Price | Quantity | |||||
AAA1047914
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Thermo Scientific Chemicals
A1047914 |
25 g |
Each for $56.78
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AAA1047922
|
Thermo Scientific Chemicals
A1047922 |
100 g |
Each for $126.00
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AAA1047936
|
Thermo Scientific Chemicals
A1047936 |
500 g |
Each for $575.25
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Description
Reagent for preparation of phosphate diesters.Phenyl phosphorodichloridate is used in the preparation of symmetrical phosphate diesters. It is used as a phosphorylating agent for alcohols and amines. It is also involved in the preparation of phenylphosphoro di-(1-imidazolidate) and 2-phenyl-bis-triazoloylphosphate, which is used in peptide synthesis. It plays a vital role in the Pfitzner-Moffatt oxidation which involves oxidation of alcohols to the corresponding aldehydes and ketones. Furthermore, it is utilized in Beckmann rearrangement for the preparation of N-phenylacetamide from acetophenone oxime.
This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.
ApplicationsReagent for preparation of phosphate diesters.Phenyl phosphorodichloridate is used in the preparation of symmetrical phosphate diesters. It is used as a phosphorylating agent for alcohols and amines. It is also involved in the preparation of phenylphosphoro di-(1-imidazolidate) and 2-phenyl-bis-triazoloylphosphate, which is used in peptide synthesis. It plays a vital role in the Pfitzner-Moffatt oxidation which involves oxidation of alcohols to the corresponding aldehydes and ketones. Furthermore, it is utilized in Beckmann rearrangement for the preparation of N-phenylacetamide from acetophenone oxime.
Solubility
Immiscible with water.
Notes
Moisture sensitive. Keep the container tightly closed in a dry and well-ventilated place. Incompatible with strong bases, alcohols and strong oxidizing agents.
Chemical Identifiers
770-12-7 | |
210.978 | |
TXFOLHZMICYNRM-UHFFFAOYSA-N | |
13038 | |
C1=CC=C(C=C1)OP(=O)(Cl)Cl |
C6H5Cl2O2P | |
MFCD00002067 | |
phenyl dichlorophosphate, phenyl phosphorodichloridate, dichlorophenoxyphosphine oxide, phosphorodichloridic acid, phenyl ester, phenylphosphoric dichloride, phenyl phosphorodichlorodate, phenoxydichlorophosphine oxide, phenyldichlorophosphate, phenoxyphosphoryl dichloride, phosphoroyl dichloride phenyl ester | |
dichlorophosphoryloxybenzene |
Specifications
770-12-7 | |
1.415 | |
112°C (233°F) | |
1.523 | |
25 g | |
511863 | |
phenyl dichlorophosphate, phenyl phosphorodichloridate, dichlorophenoxyphosphine oxide, phosphorodichloridic acid, phenyl ester, phenylphosphoric dichloride, phenyl phosphorodichlorodate, phenoxydichlorophosphine oxide, phenyldichlorophosphate, phenoxyphosphoryl dichloride, phosphoroyl dichloride phenyl ester | |
TXFOLHZMICYNRM-UHFFFAOYSA-N | |
dichlorophosphoryloxybenzene | |
13038 | |
97% |
-1°C | |
241°C to 243°C | |
C6H5Cl2O2P | |
MFCD00002067 | |
UN3265 | |
Moisture sensitive | |
Immiscible with water. | |
C1=CC=C(C=C1)OP(=O)(Cl)Cl | |
210.978 | |
210.98 | |
Phenyl phosphorodichloridate |
Safety and Handling
GHS H Statement
H314-H318-H302
Causes severe skin burns and eye damage.
Causes serious eye damage.
Harmful if swallowed.
P260-P264b-P270-P280-P303+P361+P353-P304+P340-P305+P351+P338-P310-P330-P331-P363-P501c
H302-H314
DOTInformation : Transport Hazard Class: 8; Packing Group: II; Proper Shipping Name: CORROSIVE LIQUID, ACIDIC, ORGANIC, N.O.S.
EINECSNumber : 212-220-6
RTECSNumber : TD4393000
TSCA : Yes
Recommended Storage : Ambient temperatures; Store under Nitrogen
RUO – Research Use Only