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Methyl nitroacetate, 97+%
CAS: 2483-57-0 | C3H5NO4 | 119.076 g/mol
Supplier: Thermo Scientific Chemicals L1895009
Description
Methyl nitroacetate is used in the synthesis of aromatic and heteroaromatic linear (E)-alfa-nitro-arylpentenoates. It is also used to prepare phenyliodonium ylide. Further, it is utilized in the highly enantioselective and diastereoselective copper(I)-catalyzed cyclopropanation of alkenes. In addition to this, it is employed in the production of methyl (Z)-2-nitro-3-(4-nitrophenyl)-2-propenoate through reaction with 4-nitrobenzylideneaniline.
This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.
ApplicationsMethyl nitroacetate is used in the synthesis of aromatic and heteroaromatic linear (E)-alfa-nitro-arylpentenoates. It is also used to prepare phenyliodonium ylide. Further, it is utilized in the highly enantioselective and diastereoselective copper(I)-catalyzed cyclopropanation of alkenes. In addition to this, it is employed in the production of methyl (Z)-2-nitro-3-(4-nitrophenyl)-2-propenoate through reaction with 4-nitrobenzylideneaniline.
Solubility
Miscible with ethanol, ether and most organic solvents.
Notes
Light sensitive. Incompatible withstrong bases.
Specifications
| Methyl nitroacetate | |
| 1.294 | |
| 105°C (221°F) | |
| C3H5NO4 | |
| O2NCH2CO2CH3 | |
| 10 g | |
| Light sensitive | |
| Miscible with ethanol,ether and most organic solvents. | |
| COC(=O)C[N+](=O)[O-] | |
| 119.076 | |
| 119.08 |
| 2483-57-0 | |
| 195°C to 198°C | |
| Ester-like | |
| 1.426 | |
| MFCD00075480 | |
| 1758670 | |
| methyl nitroacetate, nitroacetic acid methyl ester, acetic acid, nitro-, methyl ester, methylnitroacetate, methyl nitrozcetate, methyl nitro acetate, zlchem 149, methyl a-nitroacetate, methyl 2-nitroethanoate, acmc-1clk8 | |
| ALBSWLMUHHZLLR-UHFFFAOYSA-N | |
| methyl 2-nitroacetate | |
| 17206 | |
| 98% |
Chemical Identifiers
| 2483-57-0 | |
| 119.076 | |
| ALBSWLMUHHZLLR-UHFFFAOYSA-N | |
| 17206 | |
| COC(=O)C[N+](=O)[O-] |
| C3H5NO4 | |
| MFCD00075480 | |
| methyl nitroacetate, nitroacetic acid methyl ester, acetic acid, nitro-, methyl ester, methylnitroacetate, methyl nitrozcetate, methyl nitro acetate, zlchem 149, methyl a-nitroacetate, methyl 2-nitroethanoate, acmc-1clk8 | |
| methyl 2-nitroacetate |
Safety and Handling
GHS H Statement
H315-H319
Causes skin irritation.
Causes serious eye irritation.
P261-P264b-P271-P280-P302+P352-P304+P340-P305+P351+P338-P312-P332+P313-P362-P501c
H315-H319-H335
EINECSNumber : 219-622-0
RTECSNumber : AJ1093000
TSCA : No
Recommended Storage : Ambient temperatures
RUO – Research Use Only