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(Methoxycarbonylmethyl)triphenylphosphonium bromide, 98+%
CAS: 1779-58-4 | C21H20BrO2P | 415.27 g/mol
$66.75 - $587.00
Chemical Identifiers
CAS | 1779-58-4 |
---|---|
Molecular Formula | C21H20BrO2P |
Molecular Weight (g/mol) | 415.27 |
MDL Number | MFCD00011801 |
InChI Key | VCWBQLMDSMSVRL-UHFFFAOYSA-M |
Synonym | 2-methoxy-2-oxoethyl triphenylphosphonium bromide, methoxycarbonylmethyl triphenylphosphonium bromide, carbomethoxymethyl triphenylphosphonium bromide, methoxycarbonylmethyl triphenyl phosphonium bromide, 2-methoxy-2-oxoethyl triphenylphosphanium bromide, 2-methoxy-2-oxoethyl-triphenylphosphanium bromide, 2-methoxy-2-oxo-ethyl-triphenyl-phosphonium bromide, phosphonium, 2-methoxy-2-oxoethyl triphenyl-, bromide, acmc-209edxShow More |
PubChem CID | 2733211 |
IUPAC Name | (2-methoxy-2-oxoethyl)-triphenylphosphanium;bromide |
SMILES | [Br-].COC(=O)C[P+](C1=CC=CC=C1)(C1=CC=CC=C1)C1=CC=CC=C1 |
Catalog Number | Mfr. No. | Quantity | Price | Quantity | ||||||
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Catalog Number | Mfr. No. | Quantity | Price | Quantity | ||||||
AAA1630114
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Thermo Scientific Chemicals
A1630114 |
25 g |
Each for $66.75
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AAA1630122
|
Thermo Scientific Chemicals
A1630122 |
100 g |
Each for $186.12
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AAA1630136
|
Thermo Scientific Chemicals
A1630136 |
500 g |
Each for $587.00
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Description
(Methoxycarbonylmethyl)triphenylphosphonium bromide is a reactant for the synthesis of GSK-3 inhibitors using the Wittig reaction, substituted furanones for antifungal and cytostatic activities, photochromic dithienylethene derivatives, gem-diiodoalkanes containing allylic alcohols and highly substituted cyclopentenes and brazilanes via Au-catalyzed deoxygenative Nazarov cyclization. As reactant for asymmetric hydrogenation of α,β-unsaturated ester-phosphonates, studies of thermal decomposition of phosphonium alkyl ester salts.
This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.
Applications(Methoxycarbonylmethyl)triphenylphosphonium bromide is a reactant for the synthesis of GSK-3 inhibitors using the Wittig reaction, substituted furanones for antifungal and cytostatic activities, photochromic dithienylethene derivatives, gem-diiodoalkanes containing allylic alcohols and highly substituted cyclopentenes and brazilanes via Au-catalyzed deoxygenative Nazarov cyclization. As reactant for asymmetric hydrogenation of α,β-unsaturated ester-phosphonates, studies of thermal decomposition of phosphonium alkyl ester salts.
Solubility
Soluble in methanol(almost transparency).
Notes
Hygroscopic. Store in cool place. Keep container tightly closed in a dry and well-ventilated place. Store away from strong oxidizing agents, water, moisture.
Chemical Identifiers
1779-58-4 | |
415.27 | |
VCWBQLMDSMSVRL-UHFFFAOYSA-M | |
2733211 | |
[Br-].COC(=O)C[P+](C1=CC=CC=C1)(C1=CC=CC=C1)C1=CC=CC=C1 |
C21H20BrO2P | |
MFCD00011801 | |
2-methoxy-2-oxoethyl triphenylphosphonium bromide, methoxycarbonylmethyl triphenylphosphonium bromide, carbomethoxymethyl triphenylphosphonium bromide, methoxycarbonylmethyl triphenyl phosphonium bromide, 2-methoxy-2-oxoethyl triphenylphosphanium bromide, 2-methoxy-2-oxoethyl-triphenylphosphanium bromide, 2-methoxy-2-oxo-ethyl-triphenyl-phosphonium bromide, phosphonium, 2-methoxy-2-oxoethyl triphenyl-, bromide, acmc-209edxShow More | |
(2-methoxy-2-oxoethyl)-triphenylphosphanium;bromide |
Specifications
1779-58-4 | |
C21H20BrO2P | |
25 g | |
Hygroscopic | |
Soluble in methanol(almost transparency). | |
[Br-].COC(=O)C[P+](C1=CC=CC=C1)(C1=CC=CC=C1)C1=CC=CC=C1 | |
415.27 | |
415.28 | |
(Methoxycarbonylmethyl)triphenylphosphonium bromide |
∼163°C (decomposition) | |
MFCD00011801 | |
3812975 | |
2-methoxy-2-oxoethyl triphenylphosphonium bromide, methoxycarbonylmethyl triphenylphosphonium bromide, carbomethoxymethyl triphenylphosphonium bromide, methoxycarbonylmethyl triphenyl phosphonium bromide, 2-methoxy-2-oxoethyl triphenylphosphanium bromide, 2-methoxy-2-oxoethyl-triphenylphosphanium bromide, 2-methoxy-2-oxo-ethyl-triphenyl-phosphonium bromide, phosphonium, 2-methoxy-2-oxoethyl triphenyl-, bromide, acmc-209edx | |
VCWBQLMDSMSVRL-UHFFFAOYSA-M | |
(2-methoxy-2-oxoethyl)-triphenylphosphanium;bromide | |
2733211 | |
≥98% |
Safety and Handling
GHS H Statement
H315-H319-H335
Causes skin irritation.
Causes serious eye irritation.
May cause respiratory irritation.
P261-P264b-P271-P280-P302+P352-P304+P340-P305+P351+P338-P312-P332+P313-P362-P501c
H315-H319-H335
EINECSNumber : 217-222-0
TSCA : No
Recommended Storage : Ambient temperatures
RUO – Research Use Only