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Thermo Scientific Chemicals Lawesson's Reagent, 97%
CAS: 19172-47-5 | C14H14O2P2S4 | 404.452 g/mol
$38.11 - $1063.05
Chemical Identifiers
| CAS | 19172-47-5 |
|---|---|
| Molecular Formula | C14H14O2P2S4 |
| Molecular Weight (g/mol) | 404.452 |
| MDL Number | MFCD00005171 |
| InChI Key | CFHGBZLNZZVTAY-UHFFFAOYSA-N |
| Synonym | lawesson's reagent, lawesson reagent, 2,4-bis 4-methoxyphenyl-1,3,2,4-dithiadiphosphetane 2,4-disulfide, unii-a4125mq8rx, 1,3,2,4-dithiadiphosphetane, 2,4-bis 4-methoxyphenyl-, 2,4-disulfide, 2,4-bis 4-methoxyphenyl-2,4-dithioxo-1,3,2,4-dithiadiphosphetane, 2,4-bis 4-methoxyphenyl-1,3,2,4-dithiadiphosphetane-2,4-disulfide, 2,4-bis 4-methoxyphenyl-1,3-dithia-2,4-diphosphetane 2,4-disulfide, 2,4-bis 4-methoxyphenyl-1,3-dithia-2,4-diphosphetane 2,4-disulphide, 4-methoxyphenylthiophosphoric cyclic di thioanhydride |
| PubChem CID | 87949 |
| IUPAC Name | 2,4-bis(4-methoxyphenyl)-2,4-bis(sulfanylidene)-1,3,2$l^{5},4$l^{5}-dithiadiphosphetane |
| SMILES | COC1=CC=C(C=C1)P2(=S)SP(=S)(S2)C3=CC=C(C=C3)OC |
| Catalog Number | Mfr. No. | Quantity | Price | Quantity | |||||
|---|---|---|---|---|---|---|---|---|---|
| Catalog Number | Mfr. No. | Quantity | Price | Quantity | |||||
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AAA1453006
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Thermo Scientific Chemicals
A1453006 |
5 g |
Each for $38.11
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AAA1453014
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Thermo Scientific Chemicals
A1453014 |
25 g |
Each for $77.68
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AAA1453022
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Thermo Scientific Chemicals
A1453022 |
100 g |
Each for $252.34
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AAA1453036
|
Thermo Scientific Chemicals
A1453036 |
500 g |
Each for $1,063.05
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Description
Lawesson's reagent is a thiation agent used to convert carbonyl compounds into thiocarbonyls. It is also used to thionate enones, esters, lactones, amides, lactams and quinones. Further, it is used to prepare thiols from alcohols. It is associated with silver perchlorate and utilized as and oxophilic Lewis acid catalyst for Diels-Alder reaction of dienes with alfa, beta-unsaturated aldehydes.
This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.
ApplicationsLawesson′s reagent is a thiation agent used to convert carbonyl compounds into thiocarbonyls. It is also used to thionate enones, esters, lactones, amides, lactams and quinones. Further, it is used to prepare thiols from alcohols. It is associated with silver perchlorate and utilized as and oxophilic Lewis acid catalyst for Diels-Alder reaction of dienes with alfa, beta-unsaturated aldehydes.
Solubility
Insoluble in water.
Notes
Incompatible with strong oxidizing agents.
Chemical Identifiers
| 19172-47-5 | |
| 404.452 | |
| CFHGBZLNZZVTAY-UHFFFAOYSA-N | |
| 87949 | |
| COC1=CC=C(C=C1)P2(=S)SP(=S)(S2)C3=CC=C(C=C3)OC |
| C14H14O2P2S4 | |
| MFCD00005171 | |
| lawesson's reagent, lawesson reagent, 2,4-bis 4-methoxyphenyl-1,3,2,4-dithiadiphosphetane 2,4-disulfide, unii-a4125mq8rx, 1,3,2,4-dithiadiphosphetane, 2,4-bis 4-methoxyphenyl-, 2,4-disulfide, 2,4-bis 4-methoxyphenyl-2,4-dithioxo-1,3,2,4-dithiadiphosphetane, 2,4-bis 4-methoxyphenyl-1,3,2,4-dithiadiphosphetane-2,4-disulfide, 2,4-bis 4-methoxyphenyl-1,3-dithia-2,4-diphosphetane 2,4-disulfide, 2,4-bis 4-methoxyphenyl-1,3-dithia-2,4-diphosphetane 2,4-disulphide, 4-methoxyphenylthiophosphoric cyclic di thioanhydride | |
| 2,4-bis(4-methoxyphenyl)-2,4-bis(sulfanylidene)-1,3,2$l^{5},4$l^{5}-dithiadiphosphetane |
Specifications
| 19172-47-5 | |
| C14H14O2P2S4 | |
| 5 g | |
| 1024888 | |
| 14,5391 | |
| Insoluble in water. | |
| COC1=CC=C(C=C1)P2(=S)SP(=S)(S2)C3=CC=C(C=C3)OC | |
| 404.452 | |
| 404.47 | |
| Lawesson's Reagent |
| 221°C to 225°C | |
| MFCD00005171 | |
| UN3134 | |
| Moisture sensitive | |
| lawesson's reagent, lawesson reagent, 2,4-bis 4-methoxyphenyl-1,3,2,4-dithiadiphosphetane 2,4-disulfide, unii-a4125mq8rx, 1,3,2,4-dithiadiphosphetane, 2,4-bis 4-methoxyphenyl-, 2,4-disulfide, 2,4-bis 4-methoxyphenyl-2,4-dithioxo-1,3,2,4-dithiadiphosphetane, 2,4-bis 4-methoxyphenyl-1,3,2,4-dithiadiphosphetane-2,4-disulfide, 2,4-bis 4-methoxyphenyl-1,3-dithia-2,4-diphosphetane 2,4-disulfide, 2,4-bis 4-methoxyphenyl-1,3-dithia-2,4-diphosphetane 2,4-disulphide, 4-methoxyphenylthiophosphoric cyclic di thioanhydride | |
| CFHGBZLNZZVTAY-UHFFFAOYSA-N | |
| 2,4-bis(4-methoxyphenyl)-2,4-bis(sulfanylidene)-1,3,2$l^{5},4$l^{5}-dithiadiphosphetane | |
| 87949 | |
| 97% |
Safety and Handling
GHS H Statement
H331-H261-H302-H315-H319-H335
Toxic if inhaled.
In contact with water releases flammable gas.
Harmful if swallowed.
Causes skin irritation.
Causes serious eye irritation.
May cause respiratory irritation.
P223-P231+P232-P280-P335+P334-P370+P378q-P501c
H261
DOTInformation : Hazard Class: 4.3; Packaging Group: II
EINECSNumber : 242-855-4
TSCA : Yes
Recommended Storage : Ambient temperatures
RUO – Research Use Only