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  7. Ethyl bromoacetate, 98%

Ethyl bromoacetate, 98%

Catalog No. AAA1044822
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AAA1044822 100 g
AAA1044836 500 g
AAA104480E 2500 g
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Catalog No. AAA1044822

Supplier: Thermo Scientific Chemicals A1044822

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Description

CAS: 105-36-2 | C4H7BrO2 | 167.002 g/mol

Ethyl bromoacetate is widely used as an alkylating reagent involved in the Reformatsky reaction to prepare the beta-hydroxy esters by reacting with carbonyl compounds. It is also used for the syntheses of witting reagent, artificial diethylstilbestrol antigen, 3-phenyl-1-naphthol and steroidal thiazolidinone derivatives. It finds applications in the preparation of reversibly photoresponsive coumarin-stabilized polymeric nanoparticles in an aqueous medium which act as a detectable drug carrier.

This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.

Applications
Ethyl bromoacetate is widely used as an alkylating reagent involved in the Reformatsky reaction to prepare the beta-hydroxy esters by reacting with carbonyl compounds. It is also used for the syntheses of witting reagent, artificial diethylstilbestrol antigen, 3-phenyl-1-naphthol and steroidal thiazolidinone derivatives. It finds applications in the preparation of reversibly photoresponsive coumarin-stabilized polymeric nanoparticles in an aqueous medium which act as a detectable drug carrier.

Solubility
Miscible with ethanol, acetone, benzene and ethyl ether. Immiscible with water.

Notes
It is a lachrymator. Incompatible with strong oxidizing agents.

Chemical Identifiers

CAS 105-36-2
Molecular Formula C4H7BrO2
Molecular Weight (g/mol) 167.002
MDL Number MFCD00000191
InChI Key PQJJJMRNHATNKG-UHFFFAOYSA-N
Synonym ethyl bromoacetate, antol, ethyl bromacetate, bromoacetic acid ethyl ester, ethyl monobromoacetate, acetic acid, bromo-, ethyl ester, ethoxycarbonylmethyl bromide, bromoacetic acid, ethyl ester, ethyl alpha-bromoacetate, ethyl bromo acetate
PubChem CID 7748
IUPAC Name ethyl 2-bromoacetate
SMILES CCOC(=O)CBr

Specifications

Melting Point °C to 38°C
Density 1.506 g/mL
Boiling Point 159°C
Flash Point 47°C (117°F)
Assay Percent Range 98%
Refractive Index 1.451
Linear Formula BrCH2CO2CH2CH3
Quantity 100 g
UN Number UN1603
Solubility Information Miscible with ethanol,acetone,benzene and ethyl ether. Immiscible with water.
Formula Weight 167
Percent Purity 98%
Chemical Name or Material Ethyl bromoacetate
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Safety and Handling

Hazard Category H226-H300+H310+H330
Hazard Statement GHS H Statement
H300-H310-H330-H226
Precautionary Statement P210-P233-P235-P240-P241-P242-P243-P260-P262-P264b-P270-P271-P280-P284-P301+P310-P303+P361+P353-P304+P340-P310-P330-P363-P370+P378q-P501c
DOTInformation Transport Hazard Class: 6.1; Packing Group: II; Proper Shipping Name: ETHYL BROMOACETATE
EINECSNumber 203-290-9
RTECSNumber AF6000000
TSCA Yes
Recommended Storage Ambient temperatures

RUO – Research Use Only