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  8. Diphenyliodonium chloride, 98+%

Diphenyliodonium chloride, 98+%

Catalog No. AAA1514930
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AAA1514909 10 g
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Catalog No. AAA1514930 Supplier Thermo Scientific Chemicals Supplier No. A1514930
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Description

CAS: 1483-72-3 | C12H10ClI | 316.57 g/mol

Diphenyliodonium chloride is used as a reagent for electrophilic phenylation . It is used as a reactant for copper-catalyzed cross coupling reactions of purinesband arylation of anilines. It is involved in the preparation of acetylenic arylselenide and (arylmethylene)oxindoles. Further, it is employed in the preparation of aryl alkynes through Sonogashira coupling reactions.

This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.

Applications
Diphenyliodonium chloride is used as a reagent for electrophilic phenylation . It is used as a reactant for copper-catalyzed cross coupling reactions of purinesband arylation of anilines. It is involved in the preparation of acetylenic arylselenide and (arylmethylene)oxindoles. Further, it is employed in the preparation of aryl alkynes through Sonogashira coupling reactions.

Solubility
Soluble in water and methanol.

Notes
Light sensitive. Incompatible with strong oxidizing agents.

Chemical Identifiers

CAS 1483-72-3
Molecular Formula C12H10ClI
Molecular Weight (g/mol) 316.57
MDL Number MFCD00011909
InChI Key RSJLWBUYLGJOBD-UHFFFAOYSA-M
Synonym diphenyliodonium chloride, diphenyliodanium chloride, iodonium, diphenyl-, chloride, diphenyliodoniumchloride, c12h10i.cl, iodonium, diphenyl-, chloride 1:1, acmc-1bxx9
PubChem CID 73870
IUPAC Name diphenyliodanium;chloride
SMILES [Cl-].[I+](C1=CC=CC=C1)C1=CC=CC=C1

Specifications

Melting Point ∼230°C (decomposition)
Quantity 250 g
UN Number UN2811
Beilstein 3574977
Sensitivity Light sensitive
Merck Index 14,7464
Solubility Information Soluble in water and methanol.
Formula Weight 316.57
Percent Purity ≥98%
Chemical Name or Material Diphenyliodonium chloride

Safety and Handling

Hazard Category H301-H315-H319-H335-H500
Hazard Statement GHS H Statement
H301-H315-H319-H335
Toxic if swallowed.
Causes skin irritation.
Causes serious eye irritation.
May cause respiratory irritation.
Precautionary Statement P261-P264b-P270-P271-P280-P301+P310-P302+P352-P304+P340-P305+P351+P338-P312-P330-P332+P313-P362-P501c
DOTInformation Transport Hazard Class: 6.1; Packing Group: III; Proper Shipping Name: TOXIC SOLIDS, ORGANIC, N.O.S.
EINECSNumber 216-049-8
RTECSNumber NN6651666
TSCA Yes
Recommended Storage Ambient temperatures

RUO – Research Use Only