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  8. Chlorotris(triphenylphosphine)rhodium(I), 97%

Chlorotris(triphenylphosphine)rhodium(I), 97%

Catalog No. p-7048414
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AA1046803 1 g
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Catalog No. AA1046803 Supplier Thermo Scientific Chemicals Supplier No. 01046803
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Description

CAS: 14694-95-2 | C54H45ClP3Rh | 925.23 g/mol

Chlorotris(triphenylphosphine)rhodium(I) is used as a homogeneous hydrogenation catalyst. It is used in the selective hydrogenation of alkenes and alkynes.

This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.

Chemical Identifiers

CAS 14694-95-2
Molecular Formula C54H45ClP3Rh
Molecular Weight (g/mol) 925.23
MDL Number MFCD00010016
InChI Key IXAYKDDZKIZSPV-UHFFFAOYSA-M
Synonym chlorotris triphenylphosphine rhodium i, chlorotris triphenylphosphine rhodium, tris triphenylphosphine rhodium i chloride, tris triphenylphosphine chlororhodium, wilkinson's catalyst, unii-0fv534bkev, tris triphenylphosphine rhodium chloride, 0fv534bkev, rhodium; triphenylphosphane; chloride
PubChem CID 84599
IUPAC Name rhodium;triphenylphosphane;chloride
SMILES [Cl-].[Rh+].C1=CC=C(C=C1)P(C1=CC=CC=C1)C1=CC=CC=C1.C1=CC=C(C=C1)P(C1=CC=CC=C1)C1=CC=CC=C1.C1=CC=C(C=C1)P(C1=CC=CC=C1)C1=CC=CC=C1

Specifications

Melting Point ∼250°C (decomposition)
Color Red
Odor Odorless
Linear Formula RhCl[(C6H5)3P]3
Quantity 1 g
Merck Index 14,10047
Solubility Information Soluble in most solvents (e;g; benzene,ethanol,chloroform,dichloromethane) but with phosphine dissociation; Reacts with O2 in solution
Formula Weight 925.23
Percent Purity 97%
Physical Form Micro Crystals
Chemical Name or Material Chlorotris(triphenylphosphine)rhodium(I)
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Safety and Handling

Hazard Category H315-H319-H335
Precautionary Statement P261-P264b-P271-P280-P302+P352-P304+P340-P305+P351+P338-P312-P332+P313-P362-P501c
EINECSNumber 238-744-5
TSCA Yes
storageNote1 2°C to 8°C
Recommended Storage Keep cold

RUO – Research Use Only