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Chlorodiphenylphosphine, 97%

Catalog No. p-7021769
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Catalog No. Quantity
AAA1424109 10 g
AAA1424118 50 g
AAA1424130 250 g
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Catalog No. AAA1424109

Supplier: Thermo Scientific Chemicals A1424109

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Description

CAS: 1079-66-9 | C12H10ClP | 220.64 g/mol

Chlorodiphenylphosphine is used to introduce the diphenylphosphinyl moiety by aryl ortho-lithiation. It is also used as an intermediate to make antioxidants, flame retardants, stabilizers, catalysts, photoinitiators, and optical brighteners. Used as a halogenation reagent for the conversion of alcohols into halides, in the preparation of solid-phase reagent for the conversion of alcohols to alkyl halides.

This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.

Applications
Chlorodiphenylphosphine is used to introduce the diphenylphosphinyl moiety by aryl ortho-lithiation. It is also used as an intermediate to make antioxidants, flame retardants, stabilizers, catalysts, photoinitiators, and optical brighteners. Used as a halogenation reagent for the conversion of alcohols into halides, in the preparation of solid-phase reagent for the conversion of alcohols to alkyl halides.

Solubility
Reacts with water.

Notes
Air and moisture sensitive. Store in cool, dry place in tightly closed containers. Store way from water and air.

Chemical Identifiers

CAS 1079-66-9
Molecular Formula C12H10ClP
Molecular Weight (g/mol) 220.64
MDL Number MFCD00000529
InChI Key XGRJZXREYAXTGV-UHFFFAOYSA-N
Synonym chlorodiphenylphosphine, diphenylchlorophosphine, diphenylphosphinous chloride, phosphinous chloride, diphenyl, p-chlorodiphenylphosphine, diphenylphosphine chloride, phosphine, chlorodiphenyl, unii-wo975pjk1y, pph2cl, chloro diphenyl phosphane
PubChem CID 66180
SMILES ClP(C1=CC=CC=C1)C1=CC=CC=C1

Specifications

Melting Point 14°C to 16°C
Density 1.204
Boiling Point 318°C to 321°C
Flash Point 138°C (280°F)
Odor Acrid
Refractive Index 1.635
Linear Formula (C6H5)2PCl
Quantity 10 g
UN Number UN3265
Beilstein 512032
Sensitivity Air and moisture sensitive
Solubility Information Reacts with water.
IUPAC Name chloro(diphenyl)phosphane
Formula Weight 220.64
Percent Purity 97%
Chemical Name or Material Chlorodiphenylphosphine
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Safety and Handling

Hazard Category H290-H302-H314-H335
Hazard Statement GHS H Statement
H314-H318-H302
Causes severe skin burns and eye damage.
Causes serious eye damage.
Harmful if swallowed.
Precautionary Statement P234-P260-P264b-P270-P271-P280-P303+P361+P353-P304+P340-P305+P351+P338-P310-P330-P331-P363-P390-P501c
DOTInformation Transport Hazard Class: 8; Packing Group: II; Proper Shipping Name: CORROSIVE LIQUID, ACIDIC, ORGANIC, N.O.S.
EINECSNumber 214-093-2
TSCA Yes
Recommended Storage Ambient temperatures; Store under Nitrogen

RUO – Research Use Only