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Chloro(1,5-cyclooctadiene)rhodium(I) dimer

Catalog No. AA10466MD
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250 mg
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AA10466MD 250 mg
AA1046603 1 g
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Catalog No. AA10466MD Supplier Thermo Scientific Chemicals Supplier No. 010466MD
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Description

CAS: 12092-47-6 | C16H24Cl2Rh2 | 493.08 g/mol

It is a widely used precursor to homogeneous catalysts. This is a chiral catalyst capable of asymmetrically hydrogenating certain prochiral alkenes. Chloro(1,5-cyclooctadiene)rhodium(I) dimer is also used in the synthesis of other metal ligands for use in catalysis.

This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.

Chemical Identifiers

CAS 12092-47-6
Molecular Formula C16H24Cl2Rh2
Molecular Weight (g/mol) 493.08
MDL Number MFCD00012415
InChI Key QSUDXYGZLAJAQU-MIXQCLKLSA-L
Synonym chloro 1,5-cyclooctadiene rhodium i dimer, 1z,5z-cycloocta-1,5-diene; rhodium; dichloride, bis 1,5-cyclooctadiene dirhodium i dichloride, 1,5-cyclooctadiene rhodium chloride dimer, ccris 5036, di-?-chlorobis 1,2,5,6-?-1,5-cyclooctadiene diiridium, rhodium-1,5-cyclooctadiene chloride, 1,5-cyclooctadiene-iridium i chloride dimer, chloro 1,5-cyclooctadiene iridium i dimer
PubChem CID 6436379
IUPAC Name (1Z,5Z)-cycloocta-1,5-diene;rhodium;dichloride
SMILES [Cl-].[Cl-].[Rh+].[Rh+].C1C\C=C/CC\C=C/1.C1C\C=C/CC\C=C/1

Specifications

Melting Point 243°C (decomposition)
Color Yellow to Orange
Odor Odorless
Quantity 250 mg
Sensitivity Air sensitive; Hygroscopic
Solubility Information Soluble in chloroform,dichloromethane,and methanol; Sparingly soluble in most common solvents.
Formula Weight 493.08
Physical Form Crystalline
Chemical Name or Material Chloro(1,5-cyclooctadiene)rhodium(I) dimer

Safety and Handling

EINECSNumber 235-157-6
TSCA Yes
Recommended Storage Ambient temperatures

RUO – Research Use Only