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Carbonyldihydridotris(triphenylphosphine)ruthenium(II), 99%

CAS: 25360-32-1 | C55H47OP3Ru | 917.97 g/mol

$250.67 - $926.78

Chemical Identifiers

CAS 25360-32-1
Molecular Formula C55H47OP3Ru
Molecular Weight (g/mol) 917.97
MDL Number MFCD00015870 MFCD00015870
InChI Key MLIYPCQSOXNTLJ-UHFFFAOYSA-N
PubChem CID 53384314
IUPAC Name carbon monoxide;hydride;ruthenium(2+);triphenylphosphane
SMILES [RuH2].[C-]#[O+].C1=CC=C(C=C1)P(C1=CC=CC=C1)C1=CC=CC=C1.C1=CC=C(C=C1)P(C1=CC=CC=C1)C1=CC=CC=C1.C1=CC=C(C=C1)P(C1=CC=CC=C1)C1=CC=CC=C1
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AA4052402
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Thermo Scientific Chemicals
04052402
0.5 g
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AA4052404
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Thermo Scientific Chemicals
04052404
2 g
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Description

Description

Carbonyldihydridotris(triphenylphosphine)ruthenium(II) is used as Catalyst for conversion of 1,4-alkynediols into pyrroles, Catalyst for oxidation of primary alcohols to methyl esters, Catalyst for rearrangement of oximes to amides, Catalyst for C-C coupling via directed C-H activation, Catalyst for enyne cyclization.

This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.

Specifications

Chemical Identifiers

25360-32-1
917.97
MLIYPCQSOXNTLJ-UHFFFAOYSA-N
carbon monoxide;hydride;ruthenium(2+);triphenylphosphane
C55H47OP3Ru
MFCD00015870 MFCD00015870
53384314
[RuH2].[C-]#[O+].C1=CC=C(C=C1)P(C1=CC=CC=C1)C1=CC=CC=C1.C1=CC=C(C=C1)P(C1=CC=CC=C1)C1=CC=CC=C1.C1=CC=C(C=C1)P(C1=CC=CC=C1)C1=CC=CC=C1

Specifications

25360-32-1
White
C55H47OP3Ru
0.5 g
Insoluble in water.
[RuH2].[C-]#[O+].C1=CC=C(C=C1)P(C1=CC=CC=C1)C1=CC=CC=C1.C1=CC=C(C=C1)P(C1=CC=CC=C1)C1=CC=CC=C1.C1=CC=C(C=C1)P(C1=CC=CC=C1)C1=CC=CC=C1
917.97
917.97
Carbonyldihydridotris(triphenylphosphine)ruthenium(II)
161°C to 163°C
99%
MFCD00015870 MFCD00015870
Light and moisture sensitive
MLIYPCQSOXNTLJ-UHFFFAOYSA-N
carbon monoxide;hydride;ruthenium(2+);triphenylphosphane
53384314
Crystals
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Safety and Handling

Safety and Handling

In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear suitable protective clothing and gloves.

P261-P264b-P270-P271-P280-P301+P312-P302+P352-P304+P340-P312-P330-P363-P501c

H302+H312+H332

TSCA : No

Recommended Storage : Ambient temperatures; Store under Nitrogen

SDS
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RUO – Research Use Only