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  8. Carbonyldihydridotris(triphenylphosphine)ruthenium(II), 99%

Carbonyldihydridotris(triphenylphosphine)ruthenium(II), 99%

Catalog No. aa4052404
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2 g
Catalog No. Quantity
AA4052404 2 g
AA4052402 0.5 g
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Catalog No. AA4052404

Supplier: Thermo Scientific Chemicals 04052404

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Description

CAS: 25360-32-1 | C55H47OP3Ru | 917.97 g/mol

Carbonyldihydridotris(triphenylphosphine)ruthenium(II) is used as Catalyst for conversion of 1,4-alkynediols into pyrroles, Catalyst for oxidation of primary alcohols to methyl esters, Catalyst for rearrangement of oximes to amides, Catalyst for C-C coupling via directed C-H activation, Catalyst for enyne cyclization.

This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.

Chemical Identifiers

CAS 25360-32-1
Molecular Formula C55H47OP3Ru
Molecular Weight (g/mol) 917.97
MDL Number MFCD00015870 MFCD00015870
InChI Key MLIYPCQSOXNTLJ-UHFFFAOYSA-N
PubChem CID 53384314
IUPAC Name carbon monoxide;hydride;ruthenium(2+);triphenylphosphane
SMILES [RuH2].[C-]#[O+].C1=CC=C(C=C1)P(C1=CC=CC=C1)C1=CC=CC=C1.C1=CC=C(C=C1)P(C1=CC=CC=C1)C1=CC=CC=C1.C1=CC=C(C=C1)P(C1=CC=CC=C1)C1=CC=CC=C1

Specifications

Melting Point 161°C to 163°C
Color White
Assay Percent Range 99%
Quantity 2 g
Sensitivity Light and moisture sensitive
Solubility Information Insoluble in water.
Formula Weight 917.97
Physical Form Crystals
Chemical Name or Material Carbonyldihydridotris(triphenylphosphine)ruthenium(II)

Safety and Handling

Hazard Category H302+H312+H332
Hazard Statement In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear suitable protective clothing and gloves.
Precautionary Statement P261-P264b-P270-P271-P280-P301+P312-P302+P352-P304+P340-P312-P330-P363-P501c
TSCA No
Recommended Storage Ambient temperatures; Store under Nitrogen

RUO – Research Use Only