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Allyltrimethylsilane, 98+%
CAS: 762-72-1 | C6H14Si | 114.263 g/mol
Supplier: Thermo Scientific Chemicals A1466218
Description
Allyltrimethylsilane is involved as a reactant in Hosomi Sakurai reaction for allylation in the presence of Lewis acid. For example, it reacts with cyclohexanone to get 1-allylcyclohexanol. It acts as a nucleophile and is involved in Carbon-Ferrier rearrangement.
This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.
ApplicationsAllyltrimethylsilane is involved as a reactant in Hosomi Sakurai reaction for allylation in the presence of Lewis acid. For example, it reacts with cyclohexanone to get 1-allylcyclohexanol. It acts as a nucleophile and is involved in Carbon-Ferrier rearrangement.
Solubility
Miscible with organic solvents. Immiscible with water.
Notes
Store in cool place. Incompatible with strong oxidizing agents and acids.
Specifications
| 85°C to 86°C | |
| 762-72-1 | |
| C6H14Si | |
| UN1993 | |
| −10°C (14°F) | |
| Miscible with organic solvents. Immiscible with water. | |
| C[Si](C)(C)CC=C | |
| 114.263 | |
| 114.27 | |
| 1.408 |
| Allyltrimethylsilane | |
| 50 g | |
| MFCD00008635 | |
| 906755 | |
| allyltrimethylsilane, silane, trimethyl-2-propenyl, trimethylallylsilane, silane, allyltrimethyl, allyl trimethylsilane, unii-8b84c337vf, ccris 2649, allyl trimethyl silane, 3-trimethylsilyl propene, allytrimethylsilane | |
| HYWCXWRMUZYRPH-UHFFFAOYSA-N | |
| trimethyl(prop-2-enyl)silane | |
| 69808 | |
| ≥98% | |
| 0.717 |
Chemical Identifiers
| 762-72-1 | |
| 114.263 | |
| HYWCXWRMUZYRPH-UHFFFAOYSA-N | |
| 69808 | |
| C[Si](C)(C)CC=C |
| C6H14Si | |
| MFCD00008635 | |
| allyltrimethylsilane, silane, trimethyl-2-propenyl, trimethylallylsilane, silane, allyltrimethyl, allyl trimethylsilane, unii-8b84c337vf, ccris 2649, allyl trimethyl silane, 3-trimethylsilyl propene, allytrimethylsilane | |
| trimethyl(prop-2-enyl)silane |
Safety and Handling
GHS H Statement
H225-H315-H319-H335
Highly flammable liquid and vapour.
Causes skin irritation.
Causes serious eye irritation.
May cause respiratory irritation.
P210-P233-P235-P240-P241-P242-P243-P261-P264b-P271-P280-P303+P361+P353-P304+P340-P305+P351+P338-P312-P332+P313-P363-P370+P378q-P501c
H225-H315-H319-H335
DOTInformation : Transport Hazard Class: 3; Packing Group: II; Proper Shipping Name: FLAMMABLE LIQUIDS, N.O.S.
EINECSNumber : 212-104-5
TSCA : Yes
Recommended Storage : Ambient temperatures
RUO – Research Use Only