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  7. 4-Methoxybenzeneboronic acid, 97+%

4-Methoxybenzeneboronic acid, 97+%

Catalog No. AAA1446203
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AAA1446206 5 g
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Catalog No. AAA1446203 Supplier Thermo Scientific Chemicals Supplier No. A1446203
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Description

CAS: 5720-07-0 | C7H9BO3 | 151.96 g/mol

4-Methoxybenzeneboronic acid is used for Suzuki-Miyaura cross-coupling reactions, Pd-catalyzed direct arylation, Highly effective synthesis using palladium-catalyzed arylation Suzuki-Miyaura cross-coupling in water, Palladium-catalyzed stereoselective Heck-type reaction, Tandem-type Pd(II)-catalyzed oxidative Heck reaction and intramolecular C-H amidation sequence, Copper-mediated ligandless aerobic fluoroalkylation of arylboronic acids with fluoroalkyl iodides, Ruthenium catalyzed direct arylation, Rh-catalyzed asymmetric conjugate addition, Ligand-free copper-catalyzed coupling.

This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.

Applications
4-Methoxybenzeneboronic acid is used for Suzuki-Miyaura cross-coupling reactions, Pd-catalyzed direct arylation, Highly effective synthesis using palladium-catalyzed arylation Suzuki-Miyaura cross-coupling in water, Palladium-catalyzed stereoselective Heck-type reaction, Tandem-type Pd(II)-catalyzed oxidative Heck reaction and intramolecular C-H amidation sequence, Copper-mediated ligandless aerobic fluoroalkylation of arylboronic acids with fluoroalkyl iodides, Ruthenium catalyzed direct arylation, Rh-catalyzed asymmetric conjugate addition, Ligand-free copper-catalyzed coupling.

Solubility
Soluble in dimethyl sulfoxide and methanol.

Notes
Store in cool place. Keep container tightly closed in a dry and well-ventilated place.

Chemical Identifiers

CAS 5720-07-0
Molecular Formula C7H9BO3
Molecular Weight (g/mol) 151.96
MDL Number MFCD00039139
InChI Key VOAAEKKFGLPLLU-UHFFFAOYSA-N
Synonym 4-methoxyphenyl boronic acid, 4-methoxybenzeneboronic acid, p-anisylboronic acid, p-methoxyphenylboronic acid, p-methoxybenzeneboronic acid, 4-methoxyphenyl boranediol, benzeneboronic acid, p-methoxy, 4-boronoanisole, 4-methoxyphenylboronicacid
PubChem CID 201262
IUPAC Name (4-methoxyphenyl)boronic acid
SMILES COC1=CC=C(C=C1)B(O)O

Specifications

Melting Point 202°C to 208°C
Quantity 1 g
Beilstein 2936912
Solubility Information Soluble in dimethyl sulfoxide and methanol.
Formula Weight 151.96
Percent Purity ≥97%
Chemical Name or Material 4-Methoxybenzeneboronic acid

Safety and Handling

Hazard Category H315-H319-H335
Hazard Statement GHS H Statement
H315-H319-H335
Causes skin irritation.
Causes serious eye irritation.
May cause respiratory irritation.
Precautionary Statement P261-P264b-P271-P280-P302+P352-P304+P340-P305+P351+P338-P312-P332+P313-P362-P501c
RTECSNumber CY8975000
TSCA No
Recommended Storage Ambient temperatures

RUO – Research Use Only