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3,4-(Methylenedioxy)aniline, 98+%

Catalog No. p-7020872
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Quantity:
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250 g
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Catalog No. Quantity
AAA1297509 10 g
AAA1297518 50 g
AAA1297530 250 g
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Catalog No. AAA1297509

Supplier: Thermo Scientific Chemicals A1297509

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Description

CAS: 14268-66-7 | C7H7NO2 | 137.138 g/mol

3,4-(Methylenedioxy)aniline is an pharmaceutically important aniline derivative. It undergoes N-alkylation with cyclic secondary alkylamines in the presence of Shvo catalyst to yield N-arylpyrrolidines. 3,4-(Methylenedioxy)aniline was used in the synthesis of γ-glutamylanilides.

This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.

Applications
3,4-(Methylenedioxy)aniline is an pharmaceutically important aniline derivative. It undergoes N-alkylation with cyclic secondary alkylamines in the presence of Shvo catalyst to yield N-arylpyrrolidines. 3,4-(Methylenedioxy)aniline was used in the synthesis of γ-glutamylanilides.

Solubility
Slightly soluble in water.

Notes
Store in cool place. Keep container tightly closed in a dry and well-ventilated place. Incompatible to strong acids, acid chlorides, acid anhydrides. Air & Light Sensitive. Stable under recommended storage conditions.

Chemical Identifiers

CAS 14268-66-7
Molecular Formula C7H7NO2
Molecular Weight (g/mol) 137.138
MDL Number MFCD00005832
InChI Key XGNXYCFREOZBOL-UHFFFAOYSA-N
Synonym 3,4-methylenedioxy aniline, benzo d 1,3 dioxol-5-amine, 5-amino-1,3-benzodioxole, 3,4-methylenedioxyaniline, 4-amino-1,2-methylenedioxybenzene, 5-aminobenzodioxole, methylenedioxyaniline, 2h-1,3-benzodioxol-5-amine, 1-amino-3,4-methylenedioxybenzene, 1-amino-3,4-dimethylenedioxybenzene
PubChem CID 84310
IUPAC Name 1,3-benzodioxol-5-amine
SMILES C1OC2=C(O1)C=C(C=C2)N

Specifications

Melting Point 40°C to 45°C
Boiling Point 144°C (16 mmHg)
Flash Point 142°C (287°F)
Quantity 10 g
UN Number UN2811
Beilstein 4919
Sensitivity Air and light sensitive
Solubility Information Slightly soluble in water.
Formula Weight 137.14
Percent Purity ≥98%
Chemical Name or Material 3,4-(Methylenedioxy)aniline
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Safety and Handling

Hazard Category H302+H312+H332
Hazard Statement GHS H Statement
H331-H302-H312-H315-H319
Toxic if inhaled.
Harmful if swallowed.
Harmful in contact with skin.
Causes skin irritation.
Causes serious eye irritation.
Precautionary Statement P261-P264b-P270-P271-P280-P301+P312-P302+P352-P304+P340-P312-P330-P363-P501c
DOTInformation Transport Hazard Class: 6.1; Packing Group: III; Proper Shipping Name: TOXIC SOLIDS, ORGANIC, N.O.S.
EINECSNumber 238-161-6
TSCA Yes
Recommended Storage Ambient temperatures

RUO – Research Use Only