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2,3-O-Isopropylidene-D-erythronolactone, 98%, Thermo Scientific Chemicals
For use in spiroannulated carbohydrate synthesis
$153.58 - $519.00
Chemical Identifiers
| CAS | 25581-41-3 |
|---|---|
| Molecular Formula | C7H10O4 |
| Molecular Weight (g/mol) | 158.15 |
| MDL Number | MFCD00134440 |
| InChI Key | WHPSMBYLYRPVGU-UHFFFAOYNA-N |
| Synonym | 2,3-o-isopropylidene-d-erythronolactone, --2,3-o-isopropylidene-d-erythronolactone, 3ar,6ar-2,2-dimethyldihydrofuro 3,4-d 1,3 dioxol-4 3ah-one, 3ar,6ar-2,2-dimethyl-6,6a-dihydro-3ah-furo 3,4-d 1,3 dioxol-4-one, 3ar,6ar-2,2-dimethyl-dihydro-3ah-furo 3,4-d 1,3 dioxol-4-one, pubchem19725, 2,3-o-isopropylidene-d-erythronolactol, d-2,3-o-isopropylidene-erythronic acid, a-lactone, 2-o,3-o-isopropylidene-d-erythronic acid gamma-lactone |
| PubChem CID | 386843 |
| IUPAC Name | (3aR,6aR)-2,2-dimethyl-6,6a-dihydro-3aH-furo[3,4-d][1,3]dioxol-4-one |
| SMILES | CC1(C)OC2COC(=O)C2O1 |
| Catalog Number | Mfr. No. | Quantity | Price | Quantity | |||||
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| Catalog Number | Mfr. No. | Quantity | Price | Quantity | |||||
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AAJ6687103
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Thermo Scientific Chemicals
J6687103 |
1 g |
Each for $153.58
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AAJ6687106
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Thermo Scientific Chemicals
J6687106 |
5 g |
Each for $519.00
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Description
It undergoes Aldol condensations with silyl ketene acetals.1 Employed in spiroannulated carbohydrate synthesis.2 Convergent syntheses of a hydroxylated indolizidine,3 carbohydrate substituted benzoquinones,4 and of the oxazole segment of calyculin5 have been accomplished using this chiral synthon.
This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.
ApplicationsIt undergoes Aldol condensations with silyl ketene acetals.1 Employed in spiroannulated carbohydrate synthesis.2 Convergent syntheses of a hydroxylated indolizidine,3 carbohydrate substituted benzoquinones,4 and of the oxazole segment of calyculin5 have been accomplished using this chiral synthon.
Solubility
Soluble in water
Notes
Store at room temperature. Incompatible with heat, oxidizing agents.
Chemical Identifiers
| 25581-41-3 | |
| 158.15 | |
| WHPSMBYLYRPVGU-UHFFFAOYNA-N | |
| 386843 | |
| CC1(C)OC2COC(=O)C2O1 |
| C7H10O4 | |
| MFCD00134440 | |
| 2,3-o-isopropylidene-d-erythronolactone, --2,3-o-isopropylidene-d-erythronolactone, 3ar,6ar-2,2-dimethyldihydrofuro 3,4-d 1,3 dioxol-4 3ah-one, 3ar,6ar-2,2-dimethyl-6,6a-dihydro-3ah-furo 3,4-d 1,3 dioxol-4-one, 3ar,6ar-2,2-dimethyl-dihydro-3ah-furo 3,4-d 1,3 dioxol-4-one, pubchem19725, 2,3-o-isopropylidene-d-erythronolactol, d-2,3-o-isopropylidene-erythronic acid, a-lactone, 2-o,3-o-isopropylidene-d-erythronic acid gamma-lactone | |
| (3aR,6aR)-2,2-dimethyl-6,6a-dihydro-3aH-furo[3,4-d][1,3]dioxol-4-one |
Specifications
| 25581-41-3 | |
| White | |
| MFCD00134440 | |
| 1282952 | |
| Soluble in water | |
| −118° (c=1 in Water) | |
| (3aR,6aR)-2,2-dimethyl-6,6a-dihydro-3aH-furo[3,4-d][1,3]dioxol-4-one | |
| 386843 | |
| 98% | |
| 2,3-O-Isopropylidene-D-erythronolactone |
| 67°C to 69°C | |
| C7H10O4 | |
| 1 g | |
| 2,3-o-isopropylidene-d-erythronolactone, --2,3-o-isopropylidene-d-erythronolactone, 3ar,6ar-2,2-dimethyldihydrofuro 3,4-d 1,3 dioxol-4 3ah-one, 3ar,6ar-2,2-dimethyl-6,6a-dihydro-3ah-furo 3,4-d 1,3 dioxol-4-one, 3ar,6ar-2,2-dimethyl-dihydro-3ah-furo 3,4-d 1,3 dioxol-4-one, pubchem19725, 2,3-o-isopropylidene-d-erythronolactol, d-2,3-o-isopropylidene-erythronic acid, a-lactone, 2-o,3-o-isopropylidene-d-erythronic acid gamma-lactone | |
| WHPSMBYLYRPVGU-UHFFFAOYNA-N | |
| CC1(C)OC2COC(=O)C2O1 | |
| 158.15 | |
| 158.15 | |
| Powder |
Safety and Handling
TSCA : No
Recommended Storage : Ambient temperatures
RUO – Research Use Only