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  6. 1-Propylphosphonic acid cyclic anhydride, 50+% w/w soln. in dichloromethane, Thermo Scientific Chemicals

1-Propylphosphonic acid cyclic anhydride, 50+% w/w soln. in dichloromethane, Thermo Scientific Chemicals

Catalog No. AAH6358309
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Catalog No. AAH6358309 Supplier Thermo Scientific Chemicals Supplier No. H6358309
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Description

1-Propylphosphonic acid cyclic anhydride is used as a reagent for amide/peptide bond formation. It is utilized for condensation reactions and alcohol oxidations. It is also used to promote the synthesis of hydroxamic acids from carboxylic acids. Further, it is employed as an efficient promoter for the Lossen rearrangement to synthesis urea and carbamate derivatives.

This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.

Applications
1-Propylphosphonic acid cyclic anhydride is used as a reagent for amide/peptide bond formation. It is utilized for condensation reactions and alcohol oxidations. It is also used to promote the synthesis of hydroxamic acids from carboxylic acids. Further, it is employed as an efficient promoter for the Lossen rearrangement to synthesis urea and carbamate derivatives.

Solubility
Miscible with dioxane, terahydrofuran, dimethyl formamide, polar and aprotic organic solvents.

Notes
Moisture sensitive. Incompatible withstrong oxidizing agents.

Chemical Identifiers

CAS 68957-94-8
Molecular Formula C9H21O6P3
Molecular Weight (g/mol) 318.182
MDL Number MFCD00006583
InChI Key PAQZWJGSJMLPMG-UHFFFAOYSA-N
Synonym 2,4,6-tripropyl-1,3,5,2,4,6-trioxatriphosphorinane-2,4,6-trioxide, 1-propanephosphonic acid cyclic anhydride, 2,4,6-tripropyl-1,3,5,2,4,6-trioxatriphosphinane 2,4,6-trioxide, unii-i6egd8839n, 1,3,5,2,4,6-trioxatriphosphorinane, 2,4,6-tripropyl-, 2,4,6-trioxide, propane phosphonic acid anhydride, 2,4,6-tripropyl-1,3,5,2,4,6-trioxatriphosphorinane 2,4,6-trioxide, 1-propanephosphonic anhydride in thf, 2,4,6-tri-n-propyl-2,4,6-trioxo-1,3,5,2,4,6-trioxatriphosphorinane, 1-propanephosphonic anhydride in toluene, t3p
PubChem CID 111923
IUPAC Name 2,4,6-tripropyl-1,3,5,2$l^{5},4$l^{5},6$l^{5}-trioxatriphosphinane 2,4,6-trioxide
SMILES CCCP1(=O)OP(=O)(OP(=O)(O1)CCC)CCC

Specifications

Quantity 10 g
UN Number UN2922
Beilstein 5079255
Solubility Information Miscible with dioxane,terahydrofuran,dimethyl formamide,polar and aprotic organic solvents.
Formula Weight 318.19
Concentration or Composition (by Analyte or Components) ≥50% w/w soln. in dichloromethane
Chemical Name or Material 1-Propylphosphonic acid cyclic anhydride

Safety and Handling

Hazard Category H314-H335-H336-H350
Hazard Statement GHS H Statement
H314-H351
Causes severe skin burns and eye damage.
Suspected of causing cancer.
Precautionary Statement P201-P202-P260-P264b-P271-P281-P301+P330+P331-P303+P361+P353-P304+P340-P305+P351+P338-P310-P363-P501c
DOTInformation Transport Hazard Class: 8; Packing Group: III; Proper Shipping Name: CORROSIVE LIQUIDS, TOXIC, N.O.S.
EINECSNumber 422-210-5
TSCA Yes
Recommended Storage Ambient temperatures

RUO – Research Use Only