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  6. 1-Propylphosphonic acid cyclic anhydride, 50+% w/w soln. in acetonitrile, Thermo Scientific Chemicals

1-Propylphosphonic acid cyclic anhydride, 50+% w/w soln. in acetonitrile, Thermo Scientific Chemicals

Catalog No. p-7041717
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250 g
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AAH6696718 50 g
AAH6696730 250 g
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Catalog No. AAH6696718 Supplier Thermo Scientific Chemicals Supplier No. H6696718
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Description

1-Propylphosphonic acid cyclic anhydride is used as a reagent for amide/peptide bond formation. It is utilized for condensation reactions and alcohol oxidations. It is also used to promote the synthesis of hydroxamic acids from carboxylic acids. Further, it is employed as an efficient promoter for the Lossen rearrangement to synthesis urea and carbamate derivatives.

This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.

Applications
1-Propylphosphonic acid cyclic anhydride is used as a reagent for amide/peptide bond formation. It is utilized for condensation reactions and alcohol oxidations. It is also used to promote the synthesis of hydroxamic acids from carboxylic acids. Further, it is employed as an efficient promoter for the Lossen rearrangement to synthesis urea and carbamate derivatives.

Solubility
Miscible with dioxane, terahydrofuran, dimethyl formamide, polar and aprotic organic solvents.

Notes
Moisture sensitive. Incompatible with strong oxidizing agents.

Chemical Identifiers

CAS 68957-94-8
Molecular Formula C9H21O6P3
Molecular Weight (g/mol) 318.182
MDL Number MFCD00006583
InChI Key PAQZWJGSJMLPMG-UHFFFAOYSA-N
Synonym 2,4,6-tripropyl-1,3,5,2,4,6-trioxatriphosphorinane-2,4,6-trioxide, 1-propanephosphonic acid cyclic anhydride, 2,4,6-tripropyl-1,3,5,2,4,6-trioxatriphosphinane 2,4,6-trioxide, unii-i6egd8839n, 1,3,5,2,4,6-trioxatriphosphorinane, 2,4,6-tripropyl-, 2,4,6-trioxide, propane phosphonic acid anhydride, 2,4,6-tripropyl-1,3,5,2,4,6-trioxatriphosphorinane 2,4,6-trioxide, 1-propanephosphonic anhydride in thf, 2,4,6-tri-n-propyl-2,4,6-trioxo-1,3,5,2,4,6-trioxatriphosphorinane, 1-propanephosphonic anhydride in toluene, t3p
PubChem CID 111923
IUPAC Name 2,4,6-tripropyl-1,3,5,2$l^{5},4$l^{5},6$l^{5}-trioxatriphosphinane 2,4,6-trioxide
SMILES CCCP1(=O)OP(=O)(OP(=O)(O1)CCC)CCC

Specifications

Quantity 50 g
UN Number UN2924
Beilstein 5079255
Solubility Information Miscible with dioxane,terahydrofuran,dimethyl formamide,polar and aprotic organic solvents.
Formula Weight 318.19
Concentration or Composition (by Analyte or Components) ≥50% w/w soln. in acetonitrile
Chemical Name or Material 1-Propylphosphonic acid cyclic anhydride

Safety and Handling

Hazard Category H225-H302+H312+H332-H314-H335
Hazard Statement GHS H Statement
H225-H314-H312
Highly flammable liquid and vapor.
Causes severe skin burns and eye damage.
Harmful in contact with skin.
Precautionary Statement P210-P233-P235-P240-P241-P242-P243-P260-P264b-P270-P271-P280-P303+P361+P353-P304+P340-P305+P351+P338-P310-P330-P331-P363-P370+P378q-P501c
DOTInformation Transport Hazard Class: 3; Packing Group: II; Proper Shipping Name: FLAMMABLE LIQUIDS, CORROSIVE, N.O.S.
EINECSNumber 422-210-5
TSCA No
Recommended Storage Ambient temperatures

RUO – Research Use Only