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1-Propylphosphonic acid cyclic anhydride, 50+% w/w soln. in acetonitrile, Thermo Scientific Chemicals
$100.99 - $353.05
Chemical Identifiers
| CAS | 68957-94-8 |
|---|---|
| Molecular Formula | C9H21O6P3 |
| Molecular Weight (g/mol) | 318.182 |
| MDL Number | MFCD00006583 |
| InChI Key | PAQZWJGSJMLPMG-UHFFFAOYSA-N |
| Synonym | 2,4,6-tripropyl-1,3,5,2,4,6-trioxatriphosphorinane-2,4,6-trioxide, t3p, 1-propanephosphonic acid cyclic anhydride, unii-i6egd8839n, 1,3,5,2,4,6-trioxatriphosphorinane, 2,4,6-tripropyl-, 2,4,6-trioxide, 1,3,5,2,4,6-trioxatriphosphorinane, 2,4,6-tripropyl-, 2,4,6-trioxide, 2,4,6-tripropyl-1,3,5,2,4,6-trioxatriphosphorinane 2,4,6-trioxide, 1-propanephosphonic anhydride in thf, 1-propanephosphonic anhydride in thf, 1-propanephosphonic anhydride in toluene, 1-propanephosphonic anhydride in toluene |
| PubChem CID | 111923 |
| IUPAC Name | 2,4,6-tripropyl-1,3,5,2$l^{5},4$l^{5},6$l^{5}-trioxatriphosphinane 2,4,6-trioxide |
| SMILES | CCCP1(=O)OP(=O)(OP(=O)(O1)CCC)CCC |
| Catalog Number | Mfr. No. | Quantity | Price | Quantity | |||||
|---|---|---|---|---|---|---|---|---|---|
| Catalog Number | Mfr. No. | Quantity | Price | Quantity | |||||
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AAH6696718
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Thermo Scientific Chemicals
H6696718 |
50 g |
Each for $100.99
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AAH6696730
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Thermo Scientific Chemicals
H6696730 |
250 g |
Each for $353.05
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Description
1-Propylphosphonic acid cyclic anhydride is used as a reagent for amide/peptide bond formation. It is utilized for condensation reactions and alcohol oxidations. It is also used to promote the synthesis of hydroxamic acids from carboxylic acids. Further, it is employed as an efficient promoter for the Lossen rearrangement to synthesis urea and carbamate derivatives.
This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.
Applications1-Propylphosphonic acid cyclic anhydride is used as a reagent for amide/peptide bond formation. It is utilized for condensation reactions and alcohol oxidations. It is also used to promote the synthesis of hydroxamic acids from carboxylic acids. Further, it is employed as an efficient promoter for the Lossen rearrangement to synthesis urea and carbamate derivatives.
Solubility
Miscible with dioxane, terahydrofuran, dimethyl formamide, polar and aprotic organic solvents.
Notes
Moisture sensitive. Incompatible with strong oxidizing agents.
Chemical Identifiers
| 68957-94-8 | |
| 318.182 | |
| PAQZWJGSJMLPMG-UHFFFAOYSA-N | |
| 111923 | |
| CCCP1(=O)OP(=O)(OP(=O)(O1)CCC)CCC |
| C9H21O6P3 | |
| MFCD00006583 | |
| 2,4,6-tripropyl-1,3,5,2,4,6-trioxatriphosphorinane-2,4,6-trioxide, t3p, 1-propanephosphonic acid cyclic anhydride, unii-i6egd8839n, 1,3,5,2,4,6-trioxatriphosphorinane, 2,4,6-tripropyl-, 2,4,6-trioxide, 1,3,5,2,4,6-trioxatriphosphorinane, 2,4,6-tripropyl-, 2,4,6-trioxide, 2,4,6-tripropyl-1,3,5,2,4,6-trioxatriphosphorinane 2,4,6-trioxide, 1-propanephosphonic anhydride in thf, 1-propanephosphonic anhydride in thf, 1-propanephosphonic anhydride in toluene, 1-propanephosphonic anhydride in toluene | |
| 2,4,6-tripropyl-1,3,5,2$l^{5},4$l^{5},6$l^{5}-trioxatriphosphinane 2,4,6-trioxide |
Specifications
| 68957-94-8 | |
| MFCD00006583 | |
| UN2924 | |
| 2,4,6-tripropyl-1,3,5,2,4,6-trioxatriphosphorinane-2,4,6-trioxide, t3p, 1-propanephosphonic acid cyclic anhydride, 2,4,6-tripropyl-1,3,5,2,4,6-trioxatriphosphinane 2,4,6-trioxide, 1,3,5,2,4,6-trioxatriphosphorinane, 2,4,6-tripropyl-, 2,4,6-trioxide, 1,3,5,2,4,6-trioxatriphosphorinane, 2,4,6-tripropyl-, 2,4,6-trioxide, propane phosphonic acid anhydride, 1-propanephosphonic anhydride in thf, 1-propanephosphonic anhydride in thf, 1-propanephosphonic anhydride in toluene, 1-propanephosphonic anhydride in toluene | |
| PAQZWJGSJMLPMG-UHFFFAOYSA-N | |
| 2,4,6-tripropyl-1,3,5,2$l^{5},4$l^{5},6$l^{5}-trioxatriphosphinane 2,4,6-trioxide | |
| 111923 | |
| ≥50% w/w soln. in acetonitrile |
| C9H21O6P3 | |
| 50 g | |
| 5079255 | |
| Miscible with dioxane,terahydrofuran,dimethyl formamide,polar and aprotic organic solvents. | |
| CCCP1(=O)OP(=O)(OP(=O)(O1)CCC)CCC | |
| 318.182 | |
| 318.19 | |
| 1-Propylphosphonic acid cyclic anhydride |
Safety and Handling
GHS H Statement
H225-H314-H312
Highly flammable liquid and vapor.
Causes severe skin burns and eye damage.
Harmful in contact with skin.
P210-P233-P235-P240-P241-P242-P243-P260-P264b-P270-P271-P280-P303+P361+P353-P304+P340-P305+P351+P338-P310-P330-P331-P363-P370+P378q-P501c
H225-H302+H312+H332-H314-H335
DOTInformation : Transport Hazard Class: 3; Packing Group: II; Proper Shipping Name: FLAMMABLE LIQUIDS, CORROSIVE, N.O.S.
EINECSNumber : 422-210-5
TSCA : No
Recommended Storage : Ambient temperatures
RUO – Research Use Only