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1-Propylphosphonic acid cyclic anhydride, 50+% soln. in DMF, Thermo Scientific Chemicals
$88.99 - $349.53
Chemical Identifiers
| CAS | 68957-94-8 |
|---|---|
| Molecular Formula | C9H21O6P3 |
| Molecular Weight (g/mol) | 318.182 |
| MDL Number | MFCD00006583 |
| InChI Key | PAQZWJGSJMLPMG-UHFFFAOYSA-N |
| Synonym | 2,4,6-tripropyl-1,3,5,2,4,6-trioxatriphosphorinane-2,4,6-trioxide, t3p, 2,4,6-tripropyl-1,3,5,2,4,6-trioxatriphosphinane 2,4,6-trioxide, 2,4,6-tripropyl-1,3,5,2,4,6-trioxatriphosphinane 2,4,6-trioxide, unii-i6egd8839n, propane phosphonic acid anhydride, 2,4,6-tripropyl-1,3,5,2,4,6-trioxatriphosphorinane 2,4,6-trioxide, 1-propanephosphonic anhydride in thf, 1-propanephosphonic anhydride in thf, 1-propanephosphonic anhydride in toluene, 1-propanephosphonic anhydride in toluene |
| PubChem CID | 111923 |
| IUPAC Name | 2,4,6-tripropyl-1,3,5,2$l^{5},4$l^{5},6$l^{5}-trioxatriphosphinane 2,4,6-trioxide |
| SMILES | CCCP1(=O)OP(=O)(OP(=O)(O1)CCC)CCC |
| Catalog Number | Mfr. No. | Quantity | Price | Quantity | |||||
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| Catalog Number | Mfr. No. | Quantity | Price | Quantity | |||||
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AAL1927109
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Thermo Scientific Chemicals
L1927109 |
10 g |
Each for $88.99
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AAL1927118
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Thermo Scientific Chemicals
L1927118 |
50 g |
Each for $349.53
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Description
1-Propylphosphonic acid cyclic anhydride is used in the synthesis of N-acyloxythiazole-2(3H)-thiones. It is also used to promote the synthesis of hydroxamic acids from carboxylic acids. Further, it is employed as an efficient promoter for the Lossen rearrangement to synthesis urea and carbamate derivatives.
This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.
Applications1-Propylphosphonic acid cyclic anhydride is used in the synthesis of N-acyloxythiazole-2(3H)-thiones. It is also used to promote the synthesis of hydroxamic acids from carboxylic acids. Further, it is employed as an efficient promoter for the Lossen rearrangement to synthesis urea and carbamate derivatives.
Solubility
Miscible with dichloromethane, dioxane, terahydrofuran, polar and aprotic organic solvents.
Notes
Moisture sensitive. Incompatible withstrong oxidizing agents.
Chemical Identifiers
| 68957-94-8 | |
| 318.182 | |
| PAQZWJGSJMLPMG-UHFFFAOYSA-N | |
| 111923 | |
| CCCP1(=O)OP(=O)(OP(=O)(O1)CCC)CCC |
| C9H21O6P3 | |
| MFCD00006583 | |
| 2,4,6-tripropyl-1,3,5,2,4,6-trioxatriphosphorinane-2,4,6-trioxide, t3p, 2,4,6-tripropyl-1,3,5,2,4,6-trioxatriphosphinane 2,4,6-trioxide, 2,4,6-tripropyl-1,3,5,2,4,6-trioxatriphosphinane 2,4,6-trioxide, unii-i6egd8839n, propane phosphonic acid anhydride, 2,4,6-tripropyl-1,3,5,2,4,6-trioxatriphosphorinane 2,4,6-trioxide, 1-propanephosphonic anhydride in thf, 1-propanephosphonic anhydride in thf, 1-propanephosphonic anhydride in toluene, 1-propanephosphonic anhydride in toluene | |
| 2,4,6-tripropyl-1,3,5,2$l^{5},4$l^{5},6$l^{5}-trioxatriphosphinane 2,4,6-trioxide |
Specifications
| 68957-94-8 | |
| 153°C | |
| C9H21O6P3 | |
| MFCD00006583 | |
| UN3265 | |
| Moisture sensitive | |
| Miscible with dichloromethane,dioxane,terahydrofuran,polar and aprotic organic solvents. | |
| CCCP1(=O)OP(=O)(OP(=O)(O1)CCC)CCC | |
| 318.182 | |
| 318.19 | |
| 1-Propylphosphonic acid cyclic anhydride |
| 1.09 | |
| 62°C (143°F) | |
| 1.4505 | |
| 10 g | |
| 5079255 | |
| 2,4,6-tripropyl-1,3,5,2,4,6-trioxatriphosphorinane-2,4,6-trioxide, t3p, 2,4,6-tripropyl-1,3,5,2,4,6-trioxatriphosphinane 2,4,6-trioxide, unii-i6egd8839n, unii-i6egd8839n, propane phosphonic acid anhydride, propane phosphonic acid anhydride, 1-propanephosphonic anhydride in thf, 2,4,6-tri-n-propyl-2,4,6-trioxo-1,3,5,2,4,6-trioxatriphosphorinane, 1-propanephosphonic anhydride in toluene, 1-propanephosphonic anhydride in toluene | |
| PAQZWJGSJMLPMG-UHFFFAOYSA-N | |
| 2,4,6-tripropyl-1,3,5,2$l^{5},4$l^{5},6$l^{5}-trioxatriphosphinane 2,4,6-trioxide | |
| 111923 | |
| ≥50% soln. in DMF |
Safety and Handling
GHS H Statement
H360-H314-H332-H227
May damage fertility or the unborn child.
Causes severe skin burns and eye damage.
Harmful if inhaled.
Combustible liquid.
P201-P202-P210-P233-P240-P241-P242-P243-P260-P264b-P271-P281-P301+P330+P331-P303+P361+P353-P304+P340-P305+P351+P338-P310-P363-P370+P378q-P501c
H226-H314-H332-H360D
DOTInformation : Transport Hazard Class: 8; Packing Group: II; Proper Shipping Name: CORROSIVE LIQUID, ACIDIC, ORGANIC, N.O.S.
EINECSNumber : 422-210-5
TSCA : No
Recommended Storage : Ambient temperatures; Store under Nitrogen
RUO – Research Use Only