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1-Bromo-3-chlorobenzene, 99%

CAS: 108-37-2 | C6H4BrCl | 191.45 g/mol

Supplier:  Thermo Scientific Chemicals A1402636

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Catalog No. AAA1402636


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Description

Description

1-Bromo-3-chlorobenzene undergoes bromine-magnesium exchange reactions with i-PrMgCl-LiCl in THF at 0°C and is strongly accelerated by electron-withdrawing substituents. It acts as test substrate to study the application of a new catalytic system for cyanation of various aryl halides using K4[Fe(CN)6] as cyanating source.

This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.

Applications
1-Bromo-3-chlorobenzene undergoes bromine-magnesium exchange reactions with i-PrMgCl-LiCl in THF at 0°C and is strongly accelerated by electron-withdrawing substituents. It acts as test substrate to study the application of a new catalytic system for cyanation of various aryl halides using K4[Fe(CN)6] as cyanating source.

Solubility
Not miscible in water.

Notes
Stable under recommended storage conditions. Incompatible with oxidizing agents.
Specifications

Specifications

1-Bromo-3-chlorobenzene
108-37-2
195°C to 196°C
Aromatic
C6H4BrCl
1446353
Not miscible in water.
ClC1=CC=CC(Br)=C1
191.45
191.46
-22°C
1.63
500 g
1.577
MFCD00000568
3-bromochlorobenzene, m-bromochlorobenzene, 3-chlorobromobenzene, benzene, 1-bromo-3-chloro, m-chlorobromobenzene, 1-chloro-3-bromobenzene, 3-chlorophenyl bromide, m-chlorophenyl bromide, m-bromophenyl chloride, 3-bromo-1-chlorobenzene
JRGGUPZKKTVKOV-UHFFFAOYSA-N
1-bromo-3-chlorobenzene
7928
99%

Chemical Identifiers

108-37-2
191.45
JRGGUPZKKTVKOV-UHFFFAOYSA-N
7928
ClC1=CC=CC(Br)=C1
C6H4BrCl
MFCD00000568
3-bromochlorobenzene, m-bromochlorobenzene, 3-chlorobromobenzene, benzene, 1-bromo-3-chloro, m-chlorobromobenzene, 1-chloro-3-bromobenzene, 3-chlorophenyl bromide, m-chlorophenyl bromide, m-bromophenyl chloride, 3-bromo-1-chlorobenzene
1-bromo-3-chlorobenzene
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Safety and Handling

Safety and Handling

GHS H Statement
H315-H319-H335-H227
Causes skin irritation.
Causes serious eye irritation.
May cause respiratory irritation.
Combustible liquid.

P210-P235-P261-P264b-P271-P280-P302+P352-P304+P340-P305+P351+P338-P312-P332+P313-P362-P370+P378q-P501c

H227-H315-H319-H335

EINECSNumber : 203-575-8

RTECSNumber : CY9005000

TSCA : Yes

Recommended Storage : Ambient temperatures

SDS
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