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1-Bromo-3-chlorobenzene, 99%

Catalog No. p-7021619
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AAA1402622 100 g
AAA1402636 500 g
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Catalog No. AAA1402622 Supplier Thermo Scientific Chemicals Supplier No. A1402622
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Description

CAS: 108-37-2 | C6H4BrCl | 191.45 g/mol

1-Bromo-3-chlorobenzene undergoes bromine-magnesium exchange reactions with i-PrMgCl-LiCl in THF at 0°C and is strongly accelerated by electron-withdrawing substituents. It acts as test substrate to study the application of a new catalytic system for cyanation of various aryl halides using K4[Fe(CN)6] as cyanating source.

This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.

Applications
1-Bromo-3-chlorobenzene undergoes bromine-magnesium exchange reactions with i-PrMgCl-LiCl in THF at 0°C and is strongly accelerated by electron-withdrawing substituents. It acts as test substrate to study the application of a new catalytic system for cyanation of various aryl halides using K4[Fe(CN)6] as cyanating source.

Solubility
Not miscible in water.

Notes
Stable under recommended storage conditions. Incompatible with oxidizing agents.

Chemical Identifiers

CAS 108-37-2
Molecular Formula C6H4BrCl
Molecular Weight (g/mol) 191.45
MDL Number MFCD00000568
InChI Key JRGGUPZKKTVKOV-UHFFFAOYSA-N
Synonym 3-bromochlorobenzene, m-bromochlorobenzene, 3-chlorobromobenzene, benzene, 1-bromo-3-chloro, m-chlorobromobenzene, 1-chloro-3-bromobenzene, 3-chlorophenyl bromide, m-chlorophenyl bromide, m-bromophenyl chloride, 3-bromo-1-chlorobenzene
PubChem CID 7928
IUPAC Name 1-bromo-3-chlorobenzene
SMILES ClC1=CC=CC(Br)=C1

Specifications

Melting Point -22°C
Density 1.63
Boiling Point 195°C to 196°C
Quantity 100 g
Odor Aromatic
Refractive Index 1.577
Beilstein 1446353
Solubility Information Not miscible in water.
Formula Weight 191.46
Percent Purity 99%
Chemical Name or Material 1-Bromo-3-chlorobenzene
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Safety and Handling

Hazard Category H227-H315-H319-H335
Hazard Statement GHS H Statement
H315-H319-H335-H227
Causes skin irritation.
Causes serious eye irritation.
May cause respiratory irritation.
Combustible liquid.
Precautionary Statement P210-P235-P261-P264b-P271-P280-P302+P352-P304+P340-P305+P351+P338-P312-P332+P313-P362-P370+P378q-P501c
EINECSNumber 203-575-8
RTECSNumber CY9005000
TSCA Yes
Recommended Storage Ambient temperatures

RUO – Research Use Only