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  7. 1,1'-(Azodicarbonyl)dipiperidine, 97%

1,1'-(Azodicarbonyl)dipiperidine, 97%

Catalog No. AAH2771906
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Catalog No. AAH2771906 Supplier Thermo Scientific Chemicals Supplier No. H2771906
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Description

CAS: 10465-81-3 | C12H20N4O2 | 252.32 g/mol

It is used in a study of the copper-catalyzed addition of aryboronic acids to azodicarboxyl derivatives providing aryl-substituted hydrazides. It is widely used reagent for the Mitsunobu reaction. It is reactant for preparation of polyfluoroalkylated tripyrazolylmethane ligands, (-)-Hygromycin A via Mitsunobu glycosylation, optically active α,α-disubstituted amino acids via Mitsunobu reaction, aza-β-lactams through [2+2] cycloaddition reactions, glycosyl disulfides, pyridine ether PPAR agonists, S-glycosyl amino acid, building blocks for combinatorial neoglycopeptide synthesis and is a histamine H3 receptor antagonists. It is a reactant for Mitsunobu inversion reactions.

This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.

Applications
It is used in a study of the copper-catalyzed addition of aryboronic acids to azodicarboxyl derivatives providing aryl-substituted hydrazides. It is widely used reagent for the Mitsunobu reaction. It is reactant for preparation of polyfluoroalkylated tripyrazolylmethane ligands, (-)-Hygromycin A via Mitsunobu glycosylation, optically active α,α-disubstituted amino acids via Mitsunobu reaction, aza-β-lactams through [2+2] cycloaddition reactions, glycosyl disulfides, pyridine ether PPAR agonists, S-glycosyl amino acid, building blocks for combinatorial neoglycopeptide synthesis and is a histamine H3 receptor antagonists. It is a reactant for Mitsunobu inversion reactions.

Solubility
Slightly soluble in water.

Notes
Store in cool dry conditions. Incompatible with oxidizing agents.

Chemical Identifiers

CAS 10465-81-3
Molecular Formula C12H20N4O2
Molecular Weight (g/mol) 252.32
MDL Number MFCD00010111
InChI Key OQJBFFCUFALWQL-UHFFFAOYSA-N
Synonym 1,1'-azodicarbonyl-dipiperidine, 1,1-azodicarbonyl dipiperidine, 1,1'-azodicarbonyl dipiperidine, addp, diazene-1,2-diylbis piperidin-1-ylmethanone, azodicarboxylic acid dipiperidine, ne-n-piperidine-1-carbonylimino piperidine-1-carboxamide, 1,1'-azodicarbonyl dipiperidine addp, piperidyl piperidylcarbonyl diazenyl ketone, e-diazene-1,2-diylbis piperidin-1-ylmethanone
PubChem CID 5702657
IUPAC Name (NE)-N-(piperidine-1-carbonylimino)piperidine-1-carboxamide
SMILES O=C(N=NC(=O)N1CCCCC1)N1CCCCC1

Specifications

Melting Point 133°C to 136°C
Odor Odorless
Quantity 5 g
Solubility Information Slightly soluble in water.
Formula Weight 252.32
Percent Purity 97%
Chemical Name or Material 1,1'-(Azodicarbonyl)dipiperidine

Safety and Handling

Hazard Category H315-H319-H335
Hazard Statement GHS H Statement
H315-H319-H335
Causes skin irritation.
Causes serious eye irritation.
May cause respiratory irritation.
Precautionary Statement P261-P264b-P271-P280-P302+P352-P304+P340-P305+P351+P338-P312-P332+P313-P362-P501c
TSCA No
Recommended Storage Ambient temperatures

RUO – Research Use Only