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Triphenylcarbenium hexafluorophosphate, 98%
CAS: 437-17-2 | C19H15F6P | 388.29 g/mol
Supplier: Thermo Scientific Chemicals L0314018
Description
Triphenylcarbenium hexafluorophosphate is a reagent involved in Si-H and Si-Si bond activation at Pt of neutral and cationic silyl Pt bisphosphine complexes. It is used in investigations of interactions with chromium acetylacetonate nitride mononuclear complexes. It is used in double ring-opening polyaddition of spiro orthoesters. It is used as reagent in Synthesis of push-pull tropylium-fused aminoporphyrazine, Preparation of cycloheptatrienyl and tropylium calix[4]arenes, Synthesis of palladacycles containing chiral rhenium half-sandwich complex for use as a catalyst.
This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.
ApplicationsTriphenylcarbenium hexafluorophosphate is a reagent involved in Si-H and Si-Si bond activation at Pt of neutral and cationic silyl Pt bisphosphine complexes. It is used in investigations of interactions with chromium acetylacetonate nitride mononuclear complexes. It is used in double ring-opening polyaddition of spiro orthoesters. It is used as reagent in Synthesis of ″push-pull″ tropylium-fused aminoporphyrazine, Preparation of cycloheptatrienyl and tropylium calix[4]arenes, Synthesis of palladacycles containing chiral rhenium half-sandwich complex for use as a catalyst.
Solubility
Soluble in water. (27 g/L) at 25°C.
Notes
Moisture Sensitive. Store at 4°C. Store away from oxidizing agents and strong bases. Incompatible with heat and water.
Specifications
| Triphenylcarbenium hexafluorophosphate | |
| ∽160°C (decomposition) | |
| (C6H5)3CPF6 | |
| 50 g | |
| 4344297 | |
| triphenylcarbenium hexafluorophosphate, trityl hexafluorophosphate, tritylium hexafluorophosphate, triphenylmethyl hexafluorophosphate, triphenylcarbonium hexafluorophosphate, tritylium, hexafluorophosphate 1-, triphenyl-methyliuhexafluorophosphate 1-, ph3cpf6, methylium, triphenyl-, hexafluorophosphate 1-, methylium, hexafluorophosphate 1- | |
| IBTFOFOFRZKIJU-UHFFFAOYSA-N | |
| diphenylmethylbenzene;hexafluorophosphate | |
| 2723954 | |
| 98% |
| 437-17-2 | |
| C19H15F6P | |
| MFCD00013121 | |
| UN3261 | |
| Moisture sensitive | |
| Soluble in water. (27g/L) at 25°C. | |
| F[P-](F)(F)(F)(F)F.C1=CC=C(C=C1)[C+](C1=CC=CC=C1)C1=CC=CC=C1 | |
| 388.29 | |
| 388.29 |
Chemical Identifiers
| 437-17-2 | |
| 388.29 | |
| IBTFOFOFRZKIJU-UHFFFAOYSA-N | |
| 2723954 | |
| F[P-](F)(F)(F)(F)F.C1=CC=C(C=C1)[C+](C1=CC=CC=C1)C1=CC=CC=C1 |
| C19H15F6P | |
| MFCD00013121 | |
| triphenylcarbenium hexafluorophosphate, trityl hexafluorophosphate, tritylium hexafluorophosphate, triphenylmethyl hexafluorophosphate, triphenylcarbonium hexafluorophosphate, tritylium, hexafluorophosphate 1-, triphenyl-methyliuhexafluorophosphate 1-, ph3cpf6, methylium, triphenyl-, hexafluorophosphate 1-, methylium, hexafluorophosphate 1- | |
| diphenylmethylbenzene;hexafluorophosphate |
Safety and Handling
GHS H Statement
H314-H318
Causes severe skin burns and eye damage.
Causes serious eye damage.
P260-P264b-P271-P280-P301+P330+P331-P303+P361+P353-P304+P340-P305+P351+P338-P310-P363-P501c
H314-H335
DOTInformation : Transport Hazard Class: 8; Packing Group: II; Proper Shipping Name: CORROSIVE SOLID, ACIDIC, ORGANIC, N.O.S.
EINECSNumber : 207-112-0
TSCA : Yes
Recommended Storage : Store at -20°C; Store under Nitrogen
RUO – Research Use Only