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Trimethylsilyl trifluoromethanesulfonate, 99%
CAS: 27607-77-8 | C4H9F3O3SSi | 222.253 g/mol
$82.86 - $996.84
Chemical Identifiers
| CAS | 27607-77-8 |
|---|---|
| Molecular Formula | C4H9F3O3SSi |
| Molecular Weight (g/mol) | 222.253 |
| MDL Number | MFCD00000406 |
| InChI Key | FTVLMFQEYACZNP-UHFFFAOYSA-N |
| Synonym | trimethylsilyl triflate, tmsotf, trifluoromethanesulfonic acid trimethylsilyl ester, trimethylsilyl trifluoromethylsulphonate, unii-z84v0cbh9j, methanesulfonic acid, trifluoro-, trimethylsilyl ester, trimethylsilyl trifluoromethylsulfonate, trimethylsllytrifluoromethanesulphonate, trimethylsilyl trifluoromethanesulphonate, trimethylsilyltrifluoromethanesulphonateShow More |
| PubChem CID | 65367 |
| IUPAC Name | trimethylsilyl trifluoromethanesulfonate |
| SMILES | C[Si](C)(C)OS(=O)(=O)C(F)(F)F |
| Catalog Number | Mfr. No. | Quantity | Price | Quantity | |||||
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| Catalog Number | Mfr. No. | Quantity | Price | Quantity | |||||
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AAA1253509
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Thermo Scientific Chemicals
A1253509 |
10 g |
Each for $82.86
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AAA1253518
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Thermo Scientific Chemicals
A1253518 |
50 g |
Each for $266.66
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AAA1253530
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Thermo Scientific Chemicals
A1253530 |
250 g |
Each for $996.84
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Description
Trimethylsilyl trifluoromethanesulfonate is used to prepare powerful Lewis acid, difluoroboron triflate etherate in acetonitrile solvent. It is also used as a reagent in a Dieckmann-like cyclization of ester-imides and diesters. Further, it is used in the conversion of carbonyl compounds to their enol ethers. It is also employed for chemical glycosylation reactions. Its reactivity is similar to trimethylsilyl chloride and is also involved in organic synthesis.
This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.
ApplicationsTrimethylsilyl trifluoromethanesulfonate is used to prepare powerful Lewis acid, difluoroboron triflate etherate in acetonitrile solvent. It is also used as a reagent in a Dieckmann-like cyclization of ester-imides and diesters. Further, it is used in the conversion of carbonyl compounds to their enol ethers. It is also employed for chemical glycosylation reactions. Its reactivity is similar to trimethylsilyl chloride and is also involved in organic synthesis.
Solubility
Miscible with aliphatic, aromatic hydrocarbons, haloalkanes and ethers. Immiscible with water.
Notes
Moisture and air sensitive. Store in a cool place. Incompatible with strong oxidizing agents and strong bases.
Chemical Identifiers
| 27607-77-8 | |
| 222.253 | |
| FTVLMFQEYACZNP-UHFFFAOYSA-N | |
| 65367 | |
| C[Si](C)(C)OS(=O)(=O)C(F)(F)F |
| C4H9F3O3SSi | |
| MFCD00000406 | |
| trimethylsilyl triflate, tmsotf, trifluoromethanesulfonic acid trimethylsilyl ester, trimethylsilyl trifluoromethylsulphonate, unii-z84v0cbh9j, methanesulfonic acid, trifluoro-, trimethylsilyl ester, trimethylsilyl trifluoromethylsulfonate, trimethylsllytrifluoromethanesulphonate, trimethylsilyl trifluoromethanesulphonate, trimethylsilyltrifluoromethanesulphonateShow More | |
| trimethylsilyl trifluoromethanesulfonate |
Specifications
| 27607-77-8 | |
| 39°C to 40°C (12 mmHg) | |
| C4H9F3O3SSi | |
| (CH3)3SiSO3CF3 | |
| 10 g | |
| 1868911 | |
| 14,9719 | |
| Miscible with aliphatic,aromatic hydrocarbons,haloalkanes and ethers. Immiscible with water. | |
| C[Si](C)(C)OS(=O)(=O)C(F)(F)F | |
| 222.253 | |
| 222.26 | |
| Trimethylsilyl trifluoromethanesulfonate |
| 1.225 | |
| 25°C (77°F) | |
| 1.36 | |
| MFCD00000406 | |
| UN2924 | |
| Moisture sensitive | |
| trimethylsilyl triflate, tmsotf, trifluoromethanesulfonic acid trimethylsilyl ester, trimethylsilyl trifluoromethylsulphonate, unii-z84v0cbh9j, methanesulfonic acid, trifluoro-, trimethylsilyl ester, trimethylsilyl trifluoromethylsulfonate, trimethylsllytrifluoromethanesulphonate, trimethylsilyl trifluoromethanesulphonate, trimethylsilyltrifluoromethanesulphonate | |
| FTVLMFQEYACZNP-UHFFFAOYSA-N | |
| trimethylsilyl trifluoromethanesulfonate | |
| 65367 | |
| 99% |
Safety and Handling
GHS H Statement
H314-H318-H226
Causes severe skin burns and eye damage.
Causes serious eye damage.
Flammable liquid and vapour.
P210-P233-P240-P241-P242-P243-P260-P264b-P271-P280-P301+P330+P331-P303+P361+P353-P304+P340-P305+P351+P338-P310-P363-P370+P378q-P501c
H226-H314-H335
DOTInformation : Hazard Class: 8; Packaging Group: II
EINECSNumber : 248-565-4
TSCA : Yes
Recommended Storage : Ambient temperatures; Store under Nitrogen
RUO – Research Use Only