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Trimethyl borate, 99.9995+% (metals basis)

Catalog No. p-7049809
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250 g
Catalog No. Quantity
AA2297518 50 g
AA2297530 250 g
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Catalog No. AA2297518

Supplier: Thermo Scientific Chemicals 02297518

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CAS: 121-43-7 | C3H9BO3 | 103.912 g/mol

Trimethyl borate is a useful reagent in organic synthesis. It is involved in the production of resins, waxes and paints and acts as a methylation agent. As a boron source, it is used to prepare flame retardants, anti-oxidants and corrosion inhibitors. It reacts with Grignard reagents followed by hydrolysis to prepare boronic acid. It is also used as a precursor of borate esters, which finds application in the Suzuki coupling reaction. It is an intermediate in the preparation of sodium borohydride.

This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.

Chemical Identifiers

CAS 121-43-7
Molecular Formula C3H9BO3
Molecular Weight (g/mol) 103.912
MDL Number MFCD00008346
InChI Key WRECIMRULFAWHA-UHFFFAOYSA-N
Synonym trimethoxyborane, methyl borate, trimethoxyboron, boric acid, trimethyl ester, trimethylborate, boric acid trimethyl ester, trimethoxyborine, borester o, boric acid h3bo3 , trimethyl ester, b och3 3
PubChem CID 8470
ChEBI CHEBI:38913
IUPAC Name trimethyl borate
SMILES B(OC)(OC)OC

Specifications

Melting Point -34°C
Color Colorless
Density 0.915 g/mL
Boiling Point 67°C to 69°C
Flash Point -8°C (17°F)
Odor Odorless
Assay Percent Range >99.9995% (metals basis)
Refractive Index 1.361
Linear Formula (CH3O)3B
Quantity 50 g
UN Number UN2416
Beilstein 1697939
Sensitivity Moisture sensitive
Merck Index 14,9712
Solubility Information Miscible with tetrahydrofuran,ether,isoporpylamine,hexane and methanol.
Formula Weight 103.92
Percent Purity ≥99.9995%
Physical Form Liquid
Assay (metals basis)
Chemical Name or Material Trimethyl borate
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Hazard Category H225-H312-H370
Hazard Statement GHS H Statement
H225-H312
Highly flammable liquid and vapor.
Harmful in contact with skin.
Precautionary Statement P210-P233-P240-P243-P260-P264b-P270-P280-P302+P352-P312-P314-P362-P372-P374-P380-P501c
DOTInformation Transport Hazard Class: 3; Packing Group: II; Proper Shipping Name: TRIMETHYL BORATE
EINECSNumber 204-468-9
RTECSNumber ED5600000
TSCA Yes
Recommended Storage Ambient temperatures; Store under Nitrogen

RUO – Research Use Only