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tert-Butyldichlorophosphine, 98%, Thermo Scientific Chemicals

Supplier:  Thermo Scientific Chemicals H2736003

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Catalog No. AAH2736003


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Description

Description

Reactant for the synthesis of alkali metal complexes. As intermediates. tert-Butyldichlorophosphine (TBDCP) is used primarily in the preparation of monoand bidentate phosphine ligands in metal complexes for catalytic chiral asymmetric hydrogenations and other asymmetric reactions as well as transition metal coupling reactions. This reagent is also used in the preparation of other phosphines in catalytic polymerization reactions.

This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.

Applications
Reactant for the synthesis of alkali metal complexes. As intermediates. tert-Butyldichlorophosphine (TBDCP) is used primarily in the preparation of monoand bidentate phosphine ligands in metal complexes for catalytic chiral asymmetric hydrogenations and other asymmetric reactions as well as transition metal coupling reactions. This reagent is also used in the preparation of other phosphines in catalytic polymerization reactions.

Solubility
Reacts with water. Soluble in n-Pentane, n-Hexane, Ether, Toluene,THF. tert-Butyldichlorophosphine is infinitely soluble in hydrocarbon and ethereal solvents.

Notes
Air & Moisture Sensitive. Store in cool place. Keep container tightly closed in a dry and well-ventilated place. Store away from strong oxidizing agents, strong bases, air, water and moisture.
Specifications

Specifications

tert-Butyldichlorophosphine
44°C to 49°C
(CH3)3CPCl2
1 g
Air and moisture sensitive
Reacts with water. Soluble in n-Pentane,n-Hexane,Ether,Toluene,THF. tert-Butyldichlorophosphine is infinitely soluble in hydrocarbon and ethereal solvents.
CC(C)(C)P(Cl)Cl
158.99
159
25979-07-1
C4H9Cl2P
MFCD00013615
UN3261
tert-butyldichlorophosphine, t-butyldichlorophosphine, tert-c4h9pcl2, tert-butyl dichloro phosphane, phosphonous dichloride, 1,1-dimethylethyl, snpladsptpdwuup@, pubchem6471, acmc-1cmec, tert-butyl dichloro phosphine, tert-butylphosphine dichloride
NMJASRUOIRRDSX-UHFFFAOYSA-N
tert-butyl(dichloro)phosphane
117690
98%

Chemical Identifiers

25979-07-1
158.99
NMJASRUOIRRDSX-UHFFFAOYSA-N
117690
CC(C)(C)P(Cl)Cl
C4H9Cl2P
MFCD00013615
tert-butyldichlorophosphine, t-butyldichlorophosphine, tert-c4h9pcl2, tert-butyl dichloro phosphane, phosphonous dichloride, 1,1-dimethylethyl, snpladsptpdwuup@, pubchem6471, acmc-1cmec, tert-butyl dichloro phosphine, tert-butylphosphine dichloride
tert-butyl(dichloro)phosphane
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Safety and Handling

Safety and Handling

GHS H Statement
H314-H318
Causes severe skin burns and eye damage.
Causes serious eye damage.

P260-P264b-P271-P280-P301+P330+P331-P303+P361+P353-P304+P340-P305+P351+P338-P310-P363-P501c

H314-H335

DOTInformation : Transport Hazard Class: 8; Packing Group: II; Proper Shipping Name: CORROSIVE SOLID, ACIDIC, ORGANIC, N.O.S.

EINECSNumber : 247-386-9

TSCA : No

Recommended Storage : Ambient temperatures; Store under Nitrogen

SDS
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RUO – Research Use Only